Synthesis and Optical Properties of a Series of  New Tailed Porphyrinate Dipeptide

Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (9): 1434-1439. Previous Articles Next Articles

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新型光敏剂——系列尾式卟啉二肽的合成与光学性质研究

罗国添*,a,b 徐庆兵a 陈治希a 滕莉丽a

(a赣南师范学院化学与生命科学学院赣州 341000)
(b江西省有机药物化学重点实验室赣州 341000)

收稿日期:2008-11-19 修回日期:2009-01-24 发布日期:2009-12-30
通讯作者: 罗国添

Synthesis and Optical Properties of a Series of New Tailed Porphyrinate Dipeptide

Luo, Guotian ^*,a,b Xu, Qingbing ^a Chen, Zhixi ^a Teng, Lili ^a

(^a College of Chemistry and Life Science, Gannan Normal University, Ganzhou 341000)
(^b Key Laboratory of Organo-Pharmaceutical Chemistry, Jiangxi Province, Ganzhou 341000)

Received:2008-11-19 Revised:2009-01-24 Published:2009-12-30
Contact: Luo, Guotian

Abstract

A series of new tailed porphyrinate dipeptides were designed and synthesized by the reactions of 5-(4-aminophenyl)-10,15,20-triphenylporphyrin with Boc protected amino acid. The target products and in-termediates were characterized by MS, 1H NMR techniques and elemental analysis, and their optical proper-ties were researched. The yields were up to 94%. The tailed porphyrinate dipeptides have strong fluores-cence emission in the red region of the spectrum.

Key words: synthesis, optical property, tailed porphyrinate dipeptide

Cite this article

Luo, Guotian ^*,a,b Xu, Qingbing ^a Chen, Zhixi ^a Teng, Lili ^a. Synthesis and Optical Properties of a Series of New Tailed Porphyrinate Dipeptide[J]. Chin. J. Org. Chem., 2009, 29(9): 1434-1439.

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新型光敏剂——系列尾式卟啉二肽的合成与光学性质研究

Synthesis and Optical Properties of a Series of New Tailed Porphyrinate Dipeptide

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