Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (12): 1582-1585. Previous Articles     Next Articles

Reports

纯水中金属钕诱发芳香醛烯丙基化反应的研究

边延江*,胡晓红,王虎   

  1. (河北廊坊师范学院化学系 廊坊 065000)
  • 收稿日期:2006-09-21 修回日期:2007-05-30 发布日期:2007-12-04
  • 通讯作者: 边延江

Allylation Reactions of Aromatic Aldehydes with Neodymium in Water

BIAN Yan-Jiang*, HU Xiao-Hong, WANG Hu   

  1. (Department of Chemistry, Langfang Normal College, Langfang 065000)
  • Received:2006-09-21 Revised:2007-05-30 Published:2007-12-04
  • Contact: BIAN Yan-Jiang

The allylation reactions of aldehydes with allyl bromide were carried out in 76%~93% yields with Nd-SnCl2-H2O under ultrasound irradiation at room temperature for 50~60 min. The reactions in the same system gave homoallylic alcohols in 30%~86% yields without ultrasound irradiation under stirring for 3~4 h. The main advantages of the present procedure are shorter reaction time, higher yield and environmentally benign way.

Key words: allylation, water, neodymium, tin dichloride, carbonyl compound