Chin. J. Org. Chem. ›› 1990, Vol. 10 ›› Issue (3): 274-277. Previous Articles     Next Articles

Original Articles

三甲基硅氧基钠参与下的氟烷基碘与烯烃反应

陈庆云;吴建平   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1990-06-25

Reaction of fluoroalkyl iodides with olefines in sodium trimethylsilyl oxide

CHEN QINGYUN;WU JIANPING   

  • Published:1990-06-25

The addition reactions of fluoroalkyl iodides with olefines in a system of hexamethyldisiloxane and sodium methoxide was investigated. The reaction afforded fluoroalkyl olefines in good yields. Addition of p-dinitrobenzene or hydroquinone depressed the reaction significantly. Allyl ether reacted with Cl(CF2)n I in this system to give THF derivatives I. All the results indicate that an electron transfer process might be involved.

Key words: IODINE COMPOUNDS, SODIUM COMPOUNDS, NMR SPECTROMETRY, TETRAHYDROFURAN, FLUORINE ISOTOPES, ALKENE, SILOXANE, TRIMETHYLSILANES, ADDITION REACTION, HALOTHANE P

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