Synthesis of 2-azido-1,1-dinitroethylbenzene derivatives

Chin. J. Org. Chem. ›› 1998, Vol. 18 ›› Issue (2): 114-118. Previous Articles Next Articles

Original Articles

2-叠氮基-1,1-二硝基乙基取代苯衍生物的合成

阎红;管晓培

北京工业大学化学和环境工程学系;北京理工大学化工与材料学院

发布日期:1998-04-25

Synthesis of 2-azido-1,1-dinitroethylbenzene derivatives

YAN HONG

Published:1998-04-25

Abstract

The synthetic method of (2-azido-1,1-dinitroethyl)benzene derivatives was discussed in detail. By the hydroxymethylation, triflation and azidation of substituted phenyl dinitromethane potassium salt, the target compounds, such as 3-nitro-(2-azido- 1,1-dinitroethyl)benzene (4b), 4-nitro-(2-azido-1,1-dinitroethyl) benzene (4c), m-bis(2-azido-1,1-dinitroethyl)benzene (10) and p-bis(2-azido-1,1-dinitroethyl)benzene (15), were obtained.

Key words: ORGANIC SYNTHESIS, SYLVINE, NITROBENZENE P, METHANE P, BENZENE P, ORGANONITROGEN COMPOUNDS, AZIDE, ESTERIFICATION, NITRO COMPOUNDS

CLC Number:

O627

Cite this article

YAN HONG. Synthesis of 2-azido-1,1-dinitroethylbenzene derivatives[J]. Chin. J. Org. Chem., 1998, 18(2): 114-118.

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2-叠氮基-1,1-二硝基乙基取代苯衍生物的合成

Synthesis of 2-azido-1,1-dinitroethylbenzene derivatives

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