Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (04): 556-558. Previous Articles     Next Articles

Reports

固相熔融合成含4,4'-联吡啶二阳离子的哑铃型化合物

齐建永1,张青丽1,许新华*,1,黎小武1,2,贺干武1,2
王炳清1,3,卢锐亮1,方敬坤1   

  1. (1湖南大学化学化工学院 长沙 410082)
    (2邵阳学院化学系 邵阳 422400)
    (3新疆吐鲁番地区实验中学 吐鲁番 838000)
  • 收稿日期:2005-04-06 修回日期:2005-10-31 发布日期:2006-03-31
  • 通讯作者: 许新华*

Synthesis of Dumbbell-Shape Compound Contain-ing4,4'-Bipyridinium Dication under Solid Phase Fusion

QI Jian-Yong1,ZHANG Qing-Li1,XU Xin-Hua*,1,LI Xiao-Wu1,2,HE Gan-Wu1,2
WANG Bing-Qing1,3,LU Rui-Liang1,FANG Jing-Kun1   

  1. (1 College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082)
    (2 Department of Chemistry, Shaoyang University, Shaoyang 422400)
    (3 Tulufan District High School, Tulufan 838000)
  • Received:2005-04-06 Revised:2005-10-31 Published:2006-03-31
  • Contact: Xu Xin-Hua

The mixture of tosylate of 2-{2-{4-[1-phenyl-1,1'-bis(4-tert-butylphenyl)methyl]phenoxy}ethoxy}ethanol and 4,4'-bipyridine was heated to melt for 10 min, then washed with petroleum. The dumbbell-shape compound containing 4,4'-bipyridinium dication was yielded quantitatively.

Key words: uncatalyzed, dumbbell-shape compound, solid phase fusion, synthesis, solvent-free