Synthesis, Characterization and Properties of Zinc Complexes of meso-Tetrakis(2-alkoxyphenyl)porphyrin

Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (12): 1663-1666. Previous Articles Next Articles

Original Articles

meso-四(邻烷氧基苯基)卟啉合锌的合成、表征和性能研究

贺江平^a，赵鸿斌*^,a,b，常慧^b，彭圣明^a，谢琼玉^a，刘捷频^a

(^a湘潭大学化学学院湘潭 411105)
(^b东莞理工学院化学生物工程系东莞 523808)

收稿日期:2005-06-27 修回日期:2006-06-22 发布日期:2006-11-21
通讯作者: 赵鸿斌

Synthesis, Characterization and Properties of Zinc Complexes of meso-Tetrakis(2-alkoxyphenyl)porphyrin

HE Jiang-Ping^a,ZHAO Hong-Bin*^,a,b,CHANG Hui^b
PENG Sheng-Ming^a,XIE Qiong-Yu^a,LIU Jie-Pin^a

(^aCollege of Chemistry, Xiangtan University, Xiangtan 411105)
(^bFaculty of Chemical Biotechnology, Dongguan University of Technology, Dongguan 523808)

Received:2005-06-27 Revised:2006-06-22 Published:2006-11-21
Contact: ZHAO Hong-Bin

Abstract

meso-Tetrakis(2-alkoxyphenyl)porphyrin [meso-T(2-ROP)PH₂] obtained by condensation of 2-alkoxybenzaldehydes with pyrrole, reacted with zinc acetate to form corresponding complexes [meso- T(2-ROP)PZn], while nine of them were new compounds. For the first time, meso-T(2-ROP)PZn were generated as crystals or solids. Molecular structures of all synthesized compounds were confirmed by IR, UV, ¹H NMR, MS spectra and elemental analysis. Differential scanning calorimetry and polarizing microscope were used to probe the liquid crystal properties of the serial complexes. Six of them were found to exhibit liquid crystal properties. However they displayed as heated monotropic liquid crystals.

Key words: synthesis, spectral analysis, liquid crystal property, zinc complex of porphyrin

Cite this article

HE Jiang-Ping^a,ZHAO Hong-Bin*^,a,b,CHANG Hui^b
PENG Sheng-Ming^a,XIE Qiong-Yu^a,LIU Jie-Pin^a. Synthesis, Characterization and Properties of Zinc Complexes of meso-Tetrakis(2-alkoxyphenyl)porphyrin[J]. Chin. J. Org. Chem., 2006, 26(12): 1663-1666.

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meso-四(邻烷氧基苯基)卟啉合锌的合成、表征和性能研究

Synthesis, Characterization and Properties of Zinc Complexes of meso-Tetrakis(2-alkoxyphenyl)porphyrin

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