Synthesis of Di-(1-methyl-1-heptafluoro-iso-propyl)-pentafluoropropyl Peroxydicarbonate

Chin. J. Org. Chem. ›› 2006, Vol. 26 ›› Issue (06): 823-825. Previous Articles Next Articles

Original Articles

二-(1-甲基-1-七氟异丙基)五氟丙基过氧化二碳酸酯的合成

孙小玲*^,1，徐天霏²，李兴亚²，蒋锡夔²，傅伟敏²

(¹上海应用技术学院上海 200235)
(²中国科学院上海有机化学研究所上海 200032)

收稿日期:2005-10-26 修回日期:2005-12-20 发布日期:2006-05-31
通讯作者: 孙小玲

Synthesis of Di-(1-methyl-1-heptafluoro-iso-propyl)-pentafluoropropyl Peroxydicarbonate

SUN Xiao-Ling*^,1,XU Tian-Fei²,LI Xing-Ya²,JIANG Xi-Kui²,FU Wei-Min²

(¹ Shanghai Institute of Technology, Shanghai 200235)
(² Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032)

Received:2005-10-26 Revised:2005-12-20 Published:2006-05-31
Contact: SUN Xiao-Ling

Abstract

The synthesis and characterization of di-(1-methyl-1-heptafluoro-iso-propyl)-pentafluoropropyl peroxydicarbonate (1), a potential, radical precursor are described. Thus, perfluoro-2-methyl-3-pentone (2) reacted with methylmagnesium iodide to afford the corresponding alcohol. The intermediate was treated with phosgene, followed by oxidation with sodium peroxide in dichloromethane, to produce the target molecule in totally 17% yield.

Key words: polyfluoro peroxydicarbonate, synthesis, perf1uoroalkyl radical

Cite this article

SUN Xiao-Ling*^,1,XU Tian-Fei²,LI Xing-Ya²,JIANG Xi-Kui²,FU Wei-Min². Synthesis of Di-(1-methyl-1-heptafluoro-iso-propyl)-pentafluoropropyl Peroxydicarbonate[J]. Chin. J. Org. Chem., 2006, 26(06): 823-825.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Penghui Li, Qingyang Xie, Fuxian Wan, Yuanhong Zhang, Lin Jiang. Synthesis and Fungicidal Activity of Novel Substituted Pyrimidine-5-carboxamides Bearing Cyclopropyl Moiety [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 650-656.
[2]	Fakai Zou, Nengzhong Wang, Hui Yao, Hui Wang, Mingguo Liu, Nianyu Huang. Regio- and Stereo-selective Synthesis of 1β-/3R-Aryl Thiosugar [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 593-604.
[3]	Luyao Li, Zhongwen He, Zhenguo Zhang, Zhenhua Jia, Teck-Peng Loh. Application of Triaryl Carbenium in Organic Synthesis [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 421-437.
[4]	Qinggang Mei, Qinghan Li. Recent Progress of Visible Light-Induced the Synthesis of C(3) (Hetero)arylthio Indole Compounds [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 398-408.
[5]	Weiqing Yang, Yanbing Ge, Yuanyuan Chen, Ping Liu, Haiyan Fu, Menglin Ma. Design and Synthesis of Fluorescent 1,8-Napthalimide Derivatives and Their Identification of Cysteine [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 180-194.
[6]	Qianfan Zhao, Yongzheng Chen, Shiming Zhang. Application and Mechanism Study of Carbon-Based Metal-Free Catalysts in Organic Synthesis [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 137-147.
[7]	Shan Chen, Zhilin Chen, Qiong Hu, Yanshuang Meng, Yue Huang, Pingfang Tao, Liru Lu, Guobao Huang. Recognition of Bis-thiourea Tweezers to Neutral Molecules in Non-Polar Solvent [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 277-281.
[8]	Huakun Wang, Xiaolong Ren, Yining Xuan. Study of the Halide Salt Catalyzed [3＋2] Cycloaddition of α,β-Epoxy Carboxylate with Isocyanate [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 251-258.
[9]	Yukun Jin, Baoyi Ren, Fushun Liang. Visible Light-Mediated Selective C—F Bond Cleavage of Trifluoromethyl Groups and Its Application in Synthesizing gem-Difluoro-Containing Compounds [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 85-110.
[10]	Cuiyun Ma, Hailan Luo, Fuhua Zhang, Dan Guo, Shuxing Chen, Fei Wang. Green Biosynthesis, Photophysical Properties and Application of 3-Pyrrolyl BODIPY [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 216-223.
[11]	Bozhen Wang, Jie Zhang, Chunhui Nian, Mingming Jin, Miaomiao Kong, Wulan Li, Wenfei He, Jianzhang Wu. Synthesis and Antitumor Activity of 3,4-Dichlorophenyl Amides [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 232-241.
[12]	Shihang Yu, Jiawei Liu, Biyu An, Qinghua Bian, Min Wang, Jiangchun Zhong. Asymmetric Synthesis of the Contact Sex Pheromone of Neoclytus acuminatus acuminatus (Fabricius) [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 301-308.
[13]	Yang Li, Jinding Yuan, Di Zhao. Deep Eutectic Solvent of 1,3-Dimethylurea/L-(+)-Tartaric Acid for the Green Synthesis of (E)-2-Styrylquinoline-3-carboxylic Acid Derivatives [J]. Chinese Journal of Organic Chemistry, 2023, 43(9): 3268-3276.
[14]	Dandan Sui, Nannan Cen, Ruoqu Gong, Yang Chen, Wenbo Chen. Supporting-Electrolyte-Free Electrochemical Synthesis of Trifluoromethylated Oxindoles in Continuous Flow [J]. Chinese Journal of Organic Chemistry, 2023, 43(9): 3239-3245.
[15]	Ruixia Cao, Yuping Jia. Synthesis and Biological Activity of Novel Pyrrolo[2,3-d]pyrimidine Derivatives Containing Coumarin [J]. Chinese Journal of Organic Chemistry, 2023, 43(9): 3304-3311.

二-(1-甲基-1-七氟异丙基)五氟丙基过氧化二碳酸酯的合成

Synthesis of Di-(1-methyl-1-heptafluoro-iso-propyl)-pentafluoropropyl Peroxydicarbonate

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments