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Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (12): 2026-2029. Previous Articles     Next Articles

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O,O-二乙基-N-[2-(3-乙酰基-2,2-二甲基-环丁基)-乙酰] 硫代磷酰胺合成及杀虫活性研究

赵文浩a,b；梁宏艳a；陈海燕a；周 红a；林翠梧*,a   

  1. (a广西大学化学化工学院 南宁 530004)
     (b广西化工研究院 南宁 530001)
  • 收稿日期:2009-03-21 修回日期:2009-05-25 发布日期:2009-07-24
  • 通讯作者: 林翠梧 E-mail:lincuiwu@gxu.edu.cn
  • 基金资助:

    广西科技攻关项目

Synthesis of O,O-Diethyl-N-[2-(3-acetyl-2,2-dimethyl-cyclobutyl)- aceto]thiophosphoramidate and Its Insecticidal Activity

Zhao, Wenhao a,b；Liang, Hongyan a；Chen, Haiyana；Zhou, Honga；Lin, Cuiwu*,a   

  1. (a College of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004) (b Guangxi Research Institute of Chemical Industry, Nanning 530001)
  • Received:2009-03-21 Revised:2009-05-25 Published:2009-07-24
  • Contact: Lin Cui-Wu E-mail:lincuiwu@gxu.edu.cn

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The title compound, O,O-diethyl-N-[2-(3-acetyl-2,2-dimethyl-cyclobutyl)-aceto]thiophosphor- amidate 7 is a new compound, which was synthesized by the reaction of α-pinene, and structurally confirmed by IR, MS, 1H NMR, and 13C NMR techniques. The synergistic activity of the mixture of the title compound and trichlorfon to Crocidolomia pavonana (Fabricius) was evaluated by the method of co-toxicity coefficient (CTC). The primarily bioassay result showed that the mixtures of the title compound and trichlorfon had sig-nificant synergism to Crocidolomia pavonana (Fabricius), and the CTC of the mixture (3∶7) of the title compound and trichlorfon reached 226.

Key words: α-pinene, pinonic acid, thiophosphoryl amide, synthesis, insecticidal activity