Synthesis and Insecticidal Activity of 3-[2,6-Dichloro-4- (3,3-dichloroallyloxy)phenoxy]propyl Pyrazole-5- carboxylate Derivatives

Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (05): 713-718. Previous Articles Next Articles

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3-[2,6-二氯-4-(3,3-二氯烯丙氧基)苯氧基]丙基吡唑-5-羧酸酯类衍生物的合成及杀虫活性

吴同文¹，马海军*^{,2，田辉凯³，倪珏萍²，云志*^,1}

(¹南京工业大学化学化工学院南京 210009)
(²江苏省农药研究所股份有限公司南京 210019)
(³南京农业大学植物保护学院南京 210095)

收稿日期:2009-02-28 修回日期:2009-07-08 发布日期:2009-12-23
通讯作者: 云志 E-mail:yunzhi@njut.edu.cn, zyun99@hotmail.com
基金资助:
“十一五”国家科技支撑计划(No. 2006BAE01A01-3)资助项目

Synthesis and Insecticidal Activity of 3-[2,6-Dichloro-4- (3,3-dichloroallyloxy)phenoxy]propyl Pyrazole-5- carboxylate Derivatives

Wu Tongwen¹ Ma Haijun*^,2 Tian Huikai³ Ni Jueping² Yun Zhi*^,1

(¹College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009)
(²Jiangsu Pesticide Research Institute Co., Ltd, Nanjing 210019)
(³College of Plant Protection, Nanjing Agricultural University, Nanjing 210095)

Received:2009-02-28 Revised:2009-07-08 Published:2009-12-23
Contact: YUN Zhi E-mail:yunzhi@njut.edu.cn, zyun99@hotmail.com

Abstract

Fourteen novel 3-[2,6-dichloro-4-(3,3-dichloroallyloxy)phenoxy]propyl pyrazole-5-carboxylate derivatives were synthesized by the reaction of 3-[2,6-dichloro-4-(3,3-dichloroallyloxy)phenoxy]propan-1-ol with pyrazole-5-carboxylic acid derivatives, and confirmed by IR, ¹H NMR techniques and elemental analysis. The preliminary bioassay showed that the compounds exhibited good activity against lepidopterous pests.

Key words: dichloroallyloxy, pyrazole-5-carboxylate, synthesis, insecticidal activity

Cite this article

WU Tong-Wen, MA Hai-Jun, TIAN Hui-Kai, NI Jue-Ping, YUN Zhi. Synthesis and Insecticidal Activity of 3-[2,6-Dichloro-4- (3,3-dichloroallyloxy)phenoxy]propyl Pyrazole-5- carboxylate Derivatives[J]. Chin. J. Org. Chem., 2010, 30(05): 713-718.

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3-[2,6-二氯-4-(3,3-二氯烯丙氧基)苯氧基]丙基吡唑-5-羧酸酯类衍生物的合成及杀虫活性

Synthesis and Insecticidal Activity of 3-[2,6-Dichloro-4- (3,3-dichloroallyloxy)phenoxy]propyl Pyrazole-5- carboxylate Derivatives

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