Synthesis of meso-Tetra(4-carboxylphenyl)porphyrin and Metal Complex and the Selective Recognition with Carbohydrates

Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (12): 1898-1903. Previous Articles Next Articles

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meso-四(4-羧基苯基)卟啉及金属配合物的合成和对糖类的选择识别

赵胜芳*^{,1，陈年友¹，郭鑫²，王孟华²，李早英²}

(^1.黄冈师范学院化学与应用化学学院黄冈 438000)
(²武汉大学化学与分子科学学院武汉 430072)

收稿日期:2010-02-27 修回日期:2010-05-30 发布日期:2010-07-25
通讯作者: 李早英 E-mail:zyliwuc@whu.edu.cn
基金资助:
湖北省教育厅重大项目基金（No.Ｚ200727001）;湖北省自然科学基金面上项目

Synthesis of meso-Tetra(4-carboxylphenyl)porphyrin and Metal Complex and the Selective Recognition with Carbohydrates

Zhao Shengfang*^{,1 Chen Nianyou¹ Guo Xin² Wang Menghua² Li Zaoying²}

(¹College of Chemistry and Applied Chemistry, Huanggang Normal University, Huanggang 438000)
(²College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072)

Received:2010-02-27 Revised:2010-05-30 Published:2010-07-25

Abstract

meso-Tetra(4-carboxylphenyl)porphyrin (TCPP) and the zinc complex were synthesized on mi-crowave radiation and solvent-thermal methods. The molecular recognition was studied between hosts and five carbohydrates (D-glucose, D-fructose, sucrose, maltose, lactose) by the UV-Vis and fluorimetric spectrum. The result shows that TCPP and the zinc complex can exhibit a special molecular recognition property toward malcose. The TCPP and ZnTCPP compounds form 1∶2 and 1∶1 supramolecular complexes with the guests. The complex constants were 8.1×10⁷and 8.1×10³ L•mol^－1, respectively.

Key words: meso-tetra(4-carboxylphenyl)porphyrin, metal complex, UV-vis spectrum, fluorescence spec-trum, molecular recognition

Cite this article

ZHAO Sheng-Fang, CHEN Nian-You, GUO Xin, WANG Meng-Hua, LI Zao-Ying. Synthesis of meso-Tetra(4-carboxylphenyl)porphyrin and Metal Complex and the Selective Recognition with Carbohydrates[J]. Chin. J. Org. Chem., 2010, 30(12): 1898-1903.

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meso-四(4-羧基苯基)卟啉及金属配合物的合成和对糖类的选择识别

Synthesis of meso-Tetra(4-carboxylphenyl)porphyrin and Metal Complex and the Selective Recognition with Carbohydrates

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