Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (03): 336-340. Previous Articles     Next Articles

Full Papers

β,β-偶氮桥连双卟啉的合成

黄齐茂,潘威,李清,王司卫,李志远,潘志权*   

  1. (武汉工程大学绿色化工过程省部共建教育部重点实验室 武汉 430073)
  • 收稿日期:2010-08-13 修回日期:2010-09-22 发布日期:2010-10-26
  • 通讯作者: 黄齐茂 E-mail:huangqim@163.com

Synthesis of β,β-Azo Bridged Diporphyrins

HUANG Qi-Mao, PAN Wei, LI Qing, WANG Si-Wei, LI Zhi-Yuan, PAN Zhi-Quan   

  1. (Key Laboratory for Green Chemical Process of Ministry of Education, Wuhan Institute of Technology, Wuhan 430073)
  • Received:2010-08-13 Revised:2010-09-22 Published:2010-10-26

Novel β,β-azo bridged diporphyrins were synthesized through 2-nitro-5,10,15,20-tetraphenylporphyrin coupled with sodium borohydride/Pd-C as a reduction system, and their structures were characterized by UV-vis, 1H NMR, IR, mass spectra, Raman spectroscopy and elementary analysis. Their cleavage ability to pBR322 plasmid DNA had been tested by gel electropho-resis.

Key words: diporphyrins, azo bridge, synthesis, characterization

CLC Number: