Condensation Reactions between Aldehydes and 5,5-Dimethyl-1,3- cyclohexanedione in Water without Catalyst

Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (06): 814-818. Previous Articles Next Articles

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不需加催化剂在纯水相介质中进行芳香醛与5,5-二甲基-1,3-环己二酮的缩合反应

张岩¹，程梅园²，商志才*^,1

(¹浙江大学化学系杭州 310027)
(²浙江大学药学院杭州 310027)

收稿日期:2010-08-29 修回日期:2010-11-01 发布日期:2011-01-07
通讯作者: Cheng Meiyuan E-mail:cmylnling@163.com

Condensation Reactions between Aldehydes and 5,5-Dimethyl-1,3- cyclohexanedione in Water without Catalyst

Zhang Yan¹ Cheng Meiyuan² Shang Zhi-cai*^,1

(¹Department of Chemistry, Zhejiang University, Hangzhou 310027)
(²College of Pharmacy, Zhejiang University, Hangzhou 310027)

Received:2010-08-29 Revised:2010-11-01 Published:2011-01-07

An efficient, green and convenient approach for the synthesis of xanthenedione derivatives from aldehydes and 5,5-dimethyl-1,3-cyclohexanedione in the absence of any catalyst by stirring in water is described. This method provides many advantages such as environmental friendliness, high yields and simple workup procedure.

Key words: aldehyde, condensation, xanthenedione, water, green chemistry

Cite this article

ZHANG Yan, CHENG Mei-Yuan, SHANG Zhi-Cai. Condensation Reactions between Aldehydes and 5,5-Dimethyl-1,3- cyclohexanedione in Water without Catalyst[J]. Chin. J. Org. Chem., 2011, 31(06): 814-818.

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不需加催化剂在纯水相介质中进行芳香醛与5,5-二甲基-1,3-环己二酮的缩合反应

Condensation Reactions between Aldehydes and 5,5-Dimethyl-1,3- cyclohexanedione in Water without Catalyst

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