A Novel and Simple Colorimetric Anion Sensor Based on Schiff-Base Bearing Phenolic Hydroxy Group

Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (10): 1678-1678. Previous Articles Next Articles

Notes

新型含酚羟基Schiff碱化合物的比色阴离子传感器

刘阁*^,1，曹洪玉¹，邵杰²

(¹赤峰学院化学系赤峰 024000)
(²南京林业大学化学与材料科学系南京 210037)

收稿日期:2010-12-07 修回日期:2011-04-10 发布日期:2011-05-05
通讯作者: 刘阁 E-mail:liu_ge1961@163.com

A Novel and Simple Colorimetric Anion Sensor Based on Schiff-Base Bearing Phenolic Hydroxy Group

Liu Ge*^,1 Cao Hongyu¹ Shao Jie²

(¹Department of Chemistry, Chifeng University, Chifeng 024000)
(²Department of Chemistry and Materials Science, Nanjing Forestry University, Nanjing 210037)

Received:2010-12-07 Revised:2011-04-10 Published:2011-05-05

A new anion receptor bearing phenolic hydroxy group based on Schiff base 1-hydroxy-4-chlo-ride-2,4-nitro-phenylhydrazonocarboxy (1) was designed and synthesized. The binding properties of the receptor with anions such as AcO^－, , F^－, Cl^－, Br^－, I^－ were investigated by UV-Vis and fluorescent titrations. Addition of AcO^－, , F^－ results in a noteworthy change in the visible region of spectrum (approximately 130 nm red shift), accompanied by visible color changes from light yellow to pink, which can be detected by the “naked-eye”. The further insights to the nature of interactions between the sensor 1 and F^－ were investigated by ¹H NMR titration experiments in DMSO-d₆.

Key words: Schiff-base, colorimetric anion, synthesis, anion sensor, naked-eyes recognition

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LIU Ge, CAO Hong-Yu, SHAO Jie. A Novel and Simple Colorimetric Anion Sensor Based on Schiff-Base Bearing Phenolic Hydroxy Group[J]. Chin. J. Org. Chem., 2011, 31(10): 1678-1678.

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新型含酚羟基Schiff碱化合物的比色阴离子传感器

A Novel and Simple Colorimetric Anion Sensor Based on Schiff-Base Bearing Phenolic Hydroxy Group

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