Synthesis, X-ray Crystal Structure and Reaction of Dimethylphenacylsulfonium Bromide in DMSO-HBr System

Chin. J. Org. Chem. ›› 2011, Vol. 31 ›› Issue (12): 2178-2180. Previous Articles Next Articles

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DMSO-HBr体系中二甲基苯甲酰亚甲基锍盐的合成、晶体结构及反应研究

曹志凌*^,1,2，刘冰¹，刘玮炜¹，姚国伟³，程青芳¹

(¹淮海工学院化学工程学院连云港 222005)
(²江苏省海洋资源开发研究院连云港 222005)
(³北京理工大学生命学院北京 100081)

收稿日期:2011-05-31 修回日期:2011-09-20 发布日期:2011-10-25
通讯作者: 曹志凌 E-mail:zhilingcao@yahoo.com.cn

Synthesis, X-ray Crystal Structure and Reaction of Dimethylphenacylsulfonium Bromide in DMSO-HBr System

Cao Zhiling*^,1,2 Liu Bing¹ Liu Wei-wei¹ Yao Guowei³ Cheng Qingfang¹

(¹School of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005)
(²Jiangsu Marine Resources Development Research Institute, Lianyungang 222005)
(³School of Life Science, Beijing Institute of Technology, Beijing 100081)

Received:2011-05-31 Revised:2011-09-20 Published:2011-10-25
Contact: Zhi-ling CAO E-mail:zhilingcao@yahoo.com.cn

Dimethylphenacylsulfonium bromide was synthesized from acetophenone in DMSO-HBr (dimethyl sulfoxide-hydrogen bromide) system and its crystal structure was determined by X-ray diffraction analysis. Dimethylphenacylsulfonium bromide could be transformed to phenylglyoxal both in DMSO-HBr and DMSO system. These studies contributed new evidence for understanding the mechanism of the oxidation process in DMSO-HBr system.

Key words: dimethylphenacylsulfonium bromide, synthesis, crystal structure, DMSO, oxidation

Cite this article

CAO Zhi-Ling, LIU Bing, LIU Wei-Wei, YAO Guo-Wei, CHENG Qing-Fang. Synthesis, X-ray Crystal Structure and Reaction of Dimethylphenacylsulfonium Bromide in DMSO-HBr System[J]. Chin. J. Org. Chem., 2011, 31(12): 2178-2180.

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DMSO-HBr体系中二甲基苯甲酰亚甲基锍盐的合成、晶体结构及反应研究

Synthesis, X-ray Crystal Structure and Reaction of Dimethylphenacylsulfonium Bromide in DMSO-HBr System

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