Synthesis of Polyhedronylcarbonyl Chloroethylureas Using Acylfluoride in Ionic Liquid

doi:10.6023/cjoc1107222

Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (02): 344-348 .DOI: 10.6023/cjoc1107222 Previous Articles Next Articles

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多面体烷氯乙基脲的合成新方法研究

张宏雷, 朱晓鹤, 闫红, 宋秀庆

北京工业大学生命科学与生物工程学院北京 100124

收稿日期:2011-07-22 修回日期:2011-10-10 发布日期:2012-03-09
通讯作者: 闫红 E-mail:hongyan@bjut.edu.cn
基金资助:
国家自然科学基金(No. 20872009)和北京市自然科技基金(No. 200710005002)资助项目.

Synthesis of Polyhedronylcarbonyl Chloroethylureas Using Acylfluoride in Ionic Liquid

Zhang Honglei, Zhu Xiaohe, Yan Hong, Song Xiuqing

College of Life Science and Bio-engineering, Beijing University of Technology, Beijing 100124

Received:2011-07-22 Revised:2011-10-10 Published:2012-03-09
Supported by:
Project supported by the National Natural Science Foundation of China (No. 20872009), and the Natural Science Foundation of Beijing (No. 200710005002).

Twelve polyhedronylcarbonyl chloroethylureas were synthesized by the condensation of acylfluoride and chloroethylurea in the ionic liquid [bmim][BF₄] with the polyhedron dicarboxylic acids as starting materials. The structures have been characterized by ¹H NMR, ¹³C NMR and MS techniques. Comparison with the traditional methods of acylchloride as intermediate, this procedure has the advantages of better yield, simplified operation and environmental benignity.

Key words: chloroethylureas, polyhedron, ionic liquid, acylfluoride

Cite this article

Zhang Honglei, Zhu Xiaohe, Yan Hong, Song Xiuqing. Synthesis of Polyhedronylcarbonyl Chloroethylureas Using Acylfluoride in Ionic Liquid[J]. Chin. J. Org. Chem., 2012, 32(02): 344-348 .

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多面体烷氯乙基脲的合成新方法研究

Synthesis of Polyhedronylcarbonyl Chloroethylureas Using Acylfluoride in Ionic Liquid

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