Synthesis of α-Amino Phosphonates from One-Pot Three- Component Condensation Catalyzed by Bamboo Char Sulfonic Acid

doi:10.6023/cjoc1012142

Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (02): 393-396 .DOI: 10.6023/cjoc1012142 Previous Articles Next Articles

Notes

竹炭磺酸催化一锅三组分合成α-氨基膦酸酯

周晓红, 徐琼, 梁静, 伏再辉, 尹笃林

湖南师范大学精细催化合成研究所资源精细化及先进材料湖南省高校重点实验室石化新材料湖南省工程实验室长沙 410081

收稿日期:2011-02-14 修回日期:2011-07-14 发布日期:2012-03-09
通讯作者: 尹笃林 E-mail:dulin@126.com
基金资助:
国家自然科学基金(No. 20572021)和湖南省自然科学基金(No. 09JJ5006)资助项目.

Synthesis of α-Amino Phosphonates from One-Pot Three- Component Condensation Catalyzed by Bamboo Char Sulfonic Acid

Zhou Xiaohong, Xu Qiong, Liang Jing, Fu Zaihui, Yin Dulin

Key Laboratory of Resource Fine-Processing and Advanced Materials, Universities of Hunan Province, Hunan Engineering Laboratory for Petrochemical New Materials, Institute of Fine Catalysis and Synthesis, Hunan Normal University, Changsha 410081

Received:2011-02-14 Revised:2011-07-14 Published:2012-03-09
Supported by:
Project supported by the National Natural Science Foundation of China (No. 20572021), and the Natural Science Foundation of Hunan Province (No. 09JJ5006).

By using fresh bamboo condensation raw material, bamboo char sulfonic acid was obtained via sulfuric acid charring and sulfonation, which catalyzed the one-pot three-component synthesis of α-amino phosphonates by condensation of various aromatic aldehydes with aromatic amines and diethyl phosphite. Experimental results have shown that bamboo char sulfonic acids have advantages of high activity, simplicity of operation, wide range of sources and easy recycle.

Key words: bamboo char sulfonic acid, heterogeneous catalysis, one-pot reaction, α-amino phosphonates

Cite this article

Zhou Xiaohong, Xu Qiong, Liang Jing, Fu Zaihui, Yin Dulin. Synthesis of α-Amino Phosphonates from One-Pot Three- Component Condensation Catalyzed by Bamboo Char Sulfonic Acid[J]. Chin. J. Org. Chem., 2012, 32(02): 393-396 .

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竹炭磺酸催化一锅三组分合成α-氨基膦酸酯

Synthesis of α-Amino Phosphonates from One-Pot Three- Component Condensation Catalyzed by Bamboo Char Sulfonic Acid

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