Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (08): 1834-1838.DOI: 10.6023/cjoc201301055 Previous Articles     Next Articles

Notes

双缩二氨基硫脲席夫碱锰配合物催化Henry反应的研究

张鹏a, 何军b, 万宁宁a, 张维东a, 惠永海a, 解正峰a   

  1. a 石油天然气精细化工教育部&新疆维吾尔自治区重点实验室 新疆大学化学化工学院 乌鲁木齐 830046;
    b 中国石油独山子石化公司炼油厂 独山子 833600
  • 收稿日期:2013-01-22 修回日期:2013-03-23 发布日期:2013-04-07
  • 通讯作者: 解正峰 E-mail:xiezhf72@yahoo.com.cn
  • 基金资助:
    国家自然科学基金(Nos. 21262034, 20962018, 20862015, 20562011)资助项目.

Bis-thiocarbohydrazones Schiff Base Mn(II) Complex as a Catalyst for Henry Reaction

Zhang Penga, He Junb, Wan Ningninga, Zhang Weidonga, Hui Yonghaia, Xie Zhengfenga   

  1. a Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education & Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Urumqi 830046;
    b Oil Refinery of Petrochina Dushanzi Petrochemical Company, Dushanzi 833600
  • Received:2013-01-22 Revised:2013-03-23 Published:2013-04-07
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Nos. 21262034, 20962018, 20862015, 20562011).

Bis-thiocarbohydrazones Schiff base Mn(II) complex catalyzes the Henry reaction between aldehydes and nitromethane to afford β-nitroalcohol derivatives at room temperature. The remarkable advantages of this reaction were mild reaction conditions, simple workup procedure, high yield of products, less catalyst and environmental friendly.

Key words: Henry reaction, aldehydes, nitromethane, Schiff base