Pd-Catalyzed Cross-Coupling Reaction of Alkynes with Allylic Alcohol in Ionic Liquids

doi:10.6023/cjoc201306013

Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (11): 2407-2411.DOI: 10.6023/cjoc201306013 Previous Articles Next Articles

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离子液体中钯催化炔与烯丙醇的交叉偶联反应

李建晓, 杨少容

华南理工大学化学与化工学院广州 510640

收稿日期:2013-06-07 修回日期:2013-07-03 发布日期:2013-07-10
通讯作者: 杨少容 E-mail:lisryang@scut.edu.cn
基金资助:
国家自然科学基金（No. 21102047 ）和中央高校基金（No. 2012ZM0037）资助项目.

Pd-Catalyzed Cross-Coupling Reaction of Alkynes with Allylic Alcohol in Ionic Liquids

Li Jianxiao, Yang Shaorong

School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640

Received:2013-06-07 Revised:2013-07-03 Published:2013-07-10
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21102047) and the Fundamental Research Funds for the Central Universities (No. 2012ZM0037).

A Pd-catalyzed method was developed for cross-coupling reaction of a wide range of alkynes with allylic alcohol in ionic liquids. In the presence of PdBr₂, [Bmim]Br and HBr_aq, the cross-coupling products can be obtained in moderate to good yields, and the reaction displayed high regio-and stereo-selectivities. The catalyst system could be recycled four times without loss of activity.

Key words: ionic liquid, palladium-catalyst, alkyne, allylic alcohol, cross-coupling reaction

Cite this article

Li Jianxiao, Yang Shaorong. Pd-Catalyzed Cross-Coupling Reaction of Alkynes with Allylic Alcohol in Ionic Liquids[J]. Chin. J. Org. Chem., 2013, 33(11): 2407-2411.

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离子液体中钯催化炔与烯丙醇的交叉偶联反应

Pd-Catalyzed Cross-Coupling Reaction of Alkynes with Allylic Alcohol in Ionic Liquids

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