Recent Advance of Transition Metal-Catalyzed Direct C-H Bond Carboxylation with CO2

doi:10.6023/cjoc201606007

Abstract

Carbon dioxide represents the most abundant carbon source in the world. It is obvious that the utilization of CO₂ to generate chemical products will provide a new strategy for clean energy. Meanwhile, as the main product of CO₂ reactions, carboxylic acids and derivatives have wide application. Among various CO₂ involved carboxylation reactions, the direct carboxylation of C-H bond with CO₂ has attracted much attention recently, which lies in its high efficiency for the synthesis of carboxylic acids. This review summarizes the direct carboxylation of different hybrid C-H bonds with CO₂ in recent years, which focus on transition metal catalyzed reactions for the synthesis of carboxylic acids and its derivatives from CO₂.

Key words: C-H carboxylation, CO₂, Transition metal catalysis

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Zhu Qing, Wang Lu, Xia Chungu, Liu Chao. Recent Advance of Transition Metal-Catalyzed Direct C-H Bond Carboxylation with CO₂[J]. Chin. J. Org. Chem., 2016, 36(12): 2813-2821.

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过渡金属催化CO₂与C-H键直接羧化反应的研究进展 2017-2018 Awarded

Recent Advance of Transition Metal-Catalyzed Direct C-H Bond Carboxylation with CO₂

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过渡金属催化CO2与C-H键直接羧化反应的研究进展 2017-2018 Awarded