Asymmetric Hydrogenation of β-Keto Esters Catalyzed by Ruthenium Species Supported on Porous Organic Polymer

doi:10.6023/cjoc201709018

Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (3): 656-664.DOI: 10.6023/cjoc201709018 Previous Articles Next Articles

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多孔有机聚合物负载钌催化的β-酮酸酯的不对称氢化

孔胜男, Abaid Ullah Malik, 钱雪峰, 舒谋海, 肖文德

上海交通大学化学化工学院上海 200240

收稿日期:2017-09-12 修回日期:2017-11-10 发布日期:2017-11-17
通讯作者: 钱雪峰,E-mail:mhshu@sjtu.edu.cn E-mail:mhshu@sjtu.edu.cn
基金资助:
国家自然科学基金（No.21271129）资助项目.

Asymmetric Hydrogenation of β-Keto Esters Catalyzed by Ruthenium Species Supported on Porous Organic Polymer

Kong Shengnan, Malik Abaid Ullah, Qian Xuefeng, Shu Mouhai, Xiao Wende

School of Chemistry & Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240

Received:2017-09-12 Revised:2017-11-10 Published:2017-11-17
Contact: 10.6023/cjoc201709018 E-mail:mhshu@sjtu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21271129).

A porous organic polymer (POP) with chiral 2,2'-bis(diphenylphosphino)-1,1'-binaphthalene (BINAP) has been prepared and characterized by several techniques including ¹³C CP/MAS NMR, ³¹P CP/MAS NMR, fourier transform infrared spectroscopy, powder X-ray diffraction, scanning electron microscopy, transmission electron microscopy and nitrogen adsorption. The material exhibits amorphous microporous structure. After loading of ruthenium(Ⅱ) species via coordination, the composite material Ru/POP-BINAP could be used as a heterogeneous catalyst for the asymmetric hydrogenation of β-keto esters with high activity, excellent enantioselectivity and recyclability.

Key words: porous organic polymer, heterogeneous catalysis, asymmetric hydrogenation, β-keto esters

Cite this article

Kong Shengnan, Malik Abaid Ullah, Qian Xuefeng, Shu Mouhai, Xiao Wende. Asymmetric Hydrogenation of β-Keto Esters Catalyzed by Ruthenium Species Supported on Porous Organic Polymer[J]. Chin. J. Org. Chem., 2018, 38(3): 656-664.

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多孔有机聚合物负载钌催化的β-酮酸酯的不对称氢化

Asymmetric Hydrogenation of β-Keto Esters Catalyzed by Ruthenium Species Supported on Porous Organic Polymer

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