Artificial Stimuli-Responsive Catalytic Systems for Switchable Asymmetric Catalysis

doi:10.6023/cjoc202006076

Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (11): 3672-3685.DOI: 10.6023/cjoc202006076 Previous Articles Next Articles

Special Issue: 创刊四十周年专辑

用于可切换不对称催化的人工刺激响应催化体系

唐雨平^a,b, 何艳梅^a, 范青华^a,b

a 中国科学院化学研究所中国科学院分子识别与功能重点实验室北京分子科学国家研究中心北京 100190;
b 中国科学院大学化学科学学院北京 100049

收稿日期:2020-06-30 修回日期:2020-08-03 发布日期:2020-08-11
通讯作者: 何艳梅, 范青华 E-mail:heym@iccas.ac.cn;fanqh@iccas.ac.cn
基金资助:
国家自然科学基金（Nos.21772204，21521002）和中国科学院前沿科学重点研究（No.QYZDJ-SSW-SLH023）资助项目.

Artificial Stimuli-Responsive Catalytic Systems for Switchable Asymmetric Catalysis

Tang Yuping^a,b, He Yanmei^a, Fan Qinghua^a,b

a Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences(CAS), Beijing 100190;
b School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049

Received:2020-06-30 Revised:2020-08-03 Published:2020-08-11
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21772204, 21521002), and the Key Research Program of Frontier Sciences, Chinese Academy of Sciences (No. QYZDJ-SSW-SLH023).

Inspired by enzyme allosteric catalysis, the study on artificial stimuli-responsive asymmetric catalytic systems has attracted more and more attentions in recent years. In order to precisely control the catalytic activity and stereoselectivity, stimuli-responsive functionalities have been introduced into the catalyst design. A variety of asymmetric reactions featuring on/off-switchable catalysis and/or stereodivergent catalysis have been successfully achieved by using light-, coordination-, pH-and redox-driven chiral switchable catalysts. By selecting representative examples, the catalyst design principles, allosteric mechanism and their applications in switchable asymmetric reactions sre mainly introduced. At the same time, advantages and limitations of this emerging field are summarized, and perspectives for its future development are given.

Key words: asymmetric catalysis, stimuli-responsiveness, chiral switchable catalyst, allosteric catalysis, enantiodivergent catalysis

Cite this article

Tang Yuping, He Yanmei, Fan Qinghua. Artificial Stimuli-Responsive Catalytic Systems for Switchable Asymmetric Catalysis[J]. Chinese Journal of Organic Chemistry, 2020, 40(11): 3672-3685.

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用于可切换不对称催化的人工刺激响应催化体系

Artificial Stimuli-Responsive Catalytic Systems for Switchable Asymmetric Catalysis

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