Progress in Metal-Organic Supramolecular System Based on Subcomponent Self-Assembly

doi:10.6023/cjoc202012030

Abstract

Subcomponent self-assembly is the most convenient and effective method to construct diverse metal-organic supramolecular architectures. It has become a powerful research tool for assembling rapidly together through simple building blocks via formation of covalent bonds around metal ions. This review focuses on the introduction of several metal-organic supramolecular systems based on subcomponent self-assembly, including helical structures, tetrahedral structures, hexahedral structures and octahedral structures. The unique chemical microenvironment which is derived from the internal cavities of these supramolecular structures can be used for guest recognition, protection, catalysis and extraction. Finally, the future development of this field is prospected.

Key words: subcomponent self-assembly, metal-organic supramolecular system, molecular cage, guest recognition, research progress

Cite this article

Changxing Ji, Guangxia Wang, Hua Wang. Progress in Metal-Organic Supramolecular System Based on Subcomponent Self-Assembly[J]. Chinese Journal of Organic Chemistry, 2021, 41(6): 2261-2279.

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Fig. & Tab. 27

Figure 1. (a) Synthesis of 1 and 2, (b) ligand/subcomponent exchange, and (c) selection of pyridine-2-carboxaldehyde from its isomers

Figure 2. Synthesis of (a) 3 and (b) 4, and (c) self-sorting between 3 and 4 via the subcomponent self-assembly

Figure 3. (a) Synthesis of 5 and 6 via the subcomponent self-assembly, and (b) transmetalations between helicates 5~7

Figure 4. Self-sorting for complex 10 and 11 via the subcomponent self-assembly

Figure 5. Synthesis of 13 and 14 via the subcomponent self-assembly

Figure 6. Synthesis and schematic representation of triangular triple helicates 16 and 17

Figure 7. Synthesis of homochiral helicate 19 via subcomponent self-assembly

Figure 8. Helicate 22 and NDI derivative 20

Figure 9. Synthesis of helicate 24

Figure 10. Helicates 25, 26 and 27

Figure 11. Cage 29 for (a) guest recognition, selection and release, (b) protection, and (c) switch control via Diels-Alder reaction

Figure 12. Multicatalytic system

Figure 13. Synthesis of cage 33 through subcomponent self-assembly

Figure 14. (a) Synthesis of cage 35, and (b) anion exchange drived phase transfer of cage 35 for guest separation

Figure 15. One-pot synthesis of cages 39, 40 and 41 through subcomponent self-assembly

Figure 16. One-pot synthesis of cages 43 and 44 through subcomponent self-assembly

Figure 17. One-pot synthesis of cage 45 through subcomponent self-assembly

Figure 18. One-pot synthesis of cages 47 and 48 through subcomponent self-assembly

Figure 19. Synthesis of cages 50 and 51 through subcomponent self-assembly

Figure 20. Chiral cages 53~56

Figure 21. Synthesis of cage 57 and interlocked cage 58

Figure 22. Synthesis of cage 60 through subcomponent self-assembly

Figure 23. Synthesis of hexahedral cages 61~63

Figure 24. Synthesis of hexahedral cages 64~67

Figure 25. One-pot synthesis of hexahedral cage 69 through subcomponent self-assembly

Figure 26. Synthesis of octahedral cages 70 and 71 through subcomponent self-assembly

Figure 27. Synthesis of octahedral cage 73

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