Advances in Organic Photoelectrochemical Synergistic Catalysis

doi:10.6023/cjoc202105054

Abstract

Following the renaissances of organic electrochemistry and photochemistry, photoelectrochemical approach was arising as one of hot research areas by combination advantages of photocatalysis and electrocatalysis. The photoeletrocatalysis was widely applied in redox reactions, coupling reactions and beyond. The development of photoelectrochemical transformations during past five years is summarized and the related reactions are classified according to mechanism and catalyst. The current progresses and future outlooks of such method are also discussed.

Key words: organic electrochemistry, photochemistry, photoelectrochemistry, synergistic catalysis

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Guang Yang, Yanwei Wang, Youai Qiu. Advances in Organic Photoelectrochemical Synergistic Catalysis[J]. Chinese Journal of Organic Chemistry, 2021, 41(10): 3935-3947.

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Fig. & Tab. 20

Figure 1. Original electrophotocatalyzed transformations

Figure 2. Selected examples of electrophotocatalysts

Figure 3. Trisaminocyclopropenium catalyzed oxidative coupling of arenes with nitrogen heteroaromatics

Figure 4. TAC catalyzed C—H functionalization of ethers at α-position

Figure 5. Electrophotocatalytic diamination of vicinal C—H bonds

Figure 6. Dicyanoanthracene radical cation catalyzed reduction coupling of aryl halides

Figure 7. Electrophotocatalyzed C—H alkylation of heteroarenes with organotrifluoroborates

Figure 8. Electrophotocatalyzed cross-coupling of heteroarenes with aliphatic C—H bonds

Figure 9. Electrophotocatalyzed trifluoromethylations of C(sp2)—H bond

Figure 10. Electrophotocatalyzed cross-coupling of arenes and azoles

Figure 11. Electrophotocatalyzed SNAr reactions of aryl fluorides

Figure 12. Electromediated flavin catalyzed photochemical oxidation of alcohols

Figure 13. Electrophotocatalyzed intramolecular C(sp3)—H HLF reaction

Figure 14. Electrophoto- and Mn-catalyzed C(sp3)—H oxidative azidation

Figure 15. Electrophotocatalyzed C—H alkylation of heteroarenes with alkyl oxalates

Figure 16. Oxidation of C(sp3)—H bond on BiVO4 photoanode

Figure 17. Oxidative dimethoxylation of furans on WO3/BiVO4 photoanode

Figure 18. C—H bond amination of arenes on hematite photoanode

Figure 19. Continuous-flow electrophotochemical trifluoromethylations of arenes

Figure 20. Continuous-flow electrophotochemical C—H alkylation for the synthesis of acridinium photocatalysts

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