Chinese Journal of Organic Chemistry ›› 2022, Vol. 42 ›› Issue (1): 100-110.DOI: 10.6023/cjoc202106051 Previous Articles     Next Articles

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光电联合催化的研究进展

刘颖杰a,*(), 王智传a, 孟建萍a, 李晨a, 孙凯b,*()   

  1. a 哈尔滨商业大学药学院 哈尔滨 150076
    b 烟台大学化学化工学院 山东烟台 264005
  • 收稿日期:2021-06-26 修回日期:2021-08-20 发布日期:2021-09-02
  • 通讯作者: 刘颖杰, 孙凯
  • 基金资助:
    黑龙江省自然科学基金优秀青年(YQ2019B004)

Research Progress of Photoelectric Co-catalysis

Yingjie Liua(), Zhichuan Wanga, Jianping Menga, Chen Lia, Kai Sunb()   

  1. a School of Pharmacy, Harbin University of Commerce, Harbin 150076
    b School of Chemistry and Chemical Engineering, Yantai University, Yantai, Shandong 264005
  • Received:2021-06-26 Revised:2021-08-20 Published:2021-09-02
  • Contact: Yingjie Liu, Kai Sun
  • Supported by:
    Youth Project of Natural Science Foundation of Heilongjiang Province(YQ2019B004)

Photochemical and electrochemical reactions, which are mild and green, have been widely used in organic synthesis in recent years. To push the limits of both synthetic technologies, organic chemists have focused on using these two strategies to promote organic transformation in a single reaction system. A series of photoelectrochemical strategies have been developed, and the main one at present is electrochemically mediated photoredox catalysis. In addition, photoexcitation-assisted electroredox strategies have also gradually shown their potential in organic synthesis. These strategies realize the complementary advantages and disadvantages of photochemistry and electrochemistry, and can solve the problems that can not be solved by a single synthetic technology, such as removing oxidizing reducing agents that complicate the reaction, generating intermediates with high activity under mild conditions, and so on. In this paper, the research progress of photoelectrochemical strategies is summarized according to the existing photoelectric catalysis reactions, and the possible mechanism of some reactions is discussed.

Key words: photoredox catalysis, electrocatalysis, photoelectrochemistry