Synthesis and Characterization of {[(n-Bu)2Sn (O2CCHCHAr)]2O}2 and Crystal Structure of {[(n-Bu)2Sn (O2CCHCHPh)]2O}2

Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (4): 414-418. Previous Articles Next Articles

{[(n-Bu)₂Sn(O₂CCHCHAr)]₂O}₂的合成、表征和{[(n-Bu)₂Sn(O₂CCHCHPh)]₂O}₂的晶体结构

王勇, 尹汉东^*, 王传华, 马春林

聊城大学化学系聊城 252059

收稿日期:2003-08-12 修回日期:2003-10-23 接受日期:2003-10-22 发布日期:2022-09-19
基金资助:
国家自然科学基金(No. 20271025)和山东省自然科学基金(No. Y2001B02)资助项目

Synthesis and Characterization of {[(n-Bu)₂Sn (O₂CCHCHAr)]₂O}₂ and Crystal Structure of {[(n-Bu)₂Sn (O₂CCHCHPh)]₂O}₂

WANG, Yong, YIN, Han-Dong^*, WANG, Chuan-Hua, MA, Chun-Lin

Department of Chemistry, Liaocheng University, Liaocheng 252059

Received:2003-08-12 Revised:2003-10-23 Accepted:2003-10-22 Published:2022-09-19
Contact: *E-mail: handongyin@163.com

Abstract

The five organotin compounds {[(n-Bu)₂Sn (O₂CCHCHAr)]₂O}₂ were synthesized by the reaction of (n-Bu)₂SnO with ArCHCHCO₂H in 1∶1 molar ratio. The crystal structure of {[(n-Bu)₂Sn(O₂CCHCHPh)]₂O}₂ was determined by X-ray single crystal diffraction. This compound belongs to centrosymmetric dimer structure mode with a four-membered central endo-cyclic Sn₂O₂ unit in which the bridged oxygen atoms are tri-coordinated. Each bridged oxygen atom also connects with an exo-cyclic tin atom. The endo-cyclic tin atoms are five-coordinated and have coordination geometry of distorted trigonal bipyramid. The exo-cyclic tin atoms are six-coordinated and have coordination geometry of capped trigonal bipyramid with very similarly distorted mode. The crystal belongs totriclinic with space group P1-, a=1.0172(11) nm, b=1.3804(16) nm, c=1.4703(17) nm, α=106.750(18)°, β=105.61(2)°, γ=100.295(18)°, Z=1, V=1.829(4) nm^-3, D_c=1.413 g/m³, μ=1.400 mm^-1, F(000)=792, R=0.0559, wR=0.1250.

Key words: organotin compound, aromatic substituted acrylic acid, synthesis, crystal structure

Cite this article

WANG, Yong, YIN, Han-Dong, WANG, Chuan-Hua, MA, Chun-Lin. Synthesis and Characterization of {[(n-Bu)₂Sn (O₂CCHCHAr)]₂O}₂ and Crystal Structure of {[(n-Bu)₂Sn (O₂CCHCHPh)]₂O}₂[J]. Chinese Journal of Organic Chemistry, 2004, 24(4): 414-418.

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{[(n-Bu)₂Sn(O₂CCHCHAr)]₂O}₂的合成、表征和{[(n-Bu)₂Sn(O₂CCHCHPh)]₂O}₂的晶体结构

Synthesis and Characterization of {[(n-Bu)₂Sn (O₂CCHCHAr)]₂O}₂ and Crystal Structure of {[(n-Bu)₂Sn (O₂CCHCHPh)]₂O}₂

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{[(n-Bu)2Sn(O2CCHCHAr)]2O}2的合成、表征和{[(n-Bu)2Sn(O2CCHCHPh)]2O}2的晶体结构