Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (5): 472-484. Previous Articles     Next Articles

过渡金属催化的有机硼酸与不饱和键的加成反应

焦宁a, 叶龙武b, 麻生明*,a,b   

  1. a中国科学院上海有机化学研究所金属有机化学国家重点实验室 上海 200032
    b浙江大学化学系 杭州 310027
  • 收稿日期:2003-05-22 修回日期:2003-09-05 接受日期:2003-10-09 发布日期:2022-09-20

Progress in the Transition Metal-Catalyzed Addition Reaction of OrganoboronicAcids to Unsaturated Bonds

JIAO, Ninga, YE, Long-Wub, MA, Sheng-Ming*,a,b   

  1. aState Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
    bDepartment of Chemistry, Zhejiang University, Hangzhou 310027
  • Received:2003-05-22 Revised:2003-09-05 Accepted:2003-10-09 Published:2022-09-20
  • Contact: *E-mail: masm@mail.sioc.ac.cn

Organoboronic acids enjoy high prestige in the metal-catalyzed C—Cbond formation. The cross-coupling reaction of organoboron compound has been proved to be a quite general technique for a wide range of selective C—C bondformation. In the past few years, much attention has been paid to the transition metal-catalyzed addition of organoboronic acids to unsaturated C—C bond, aldehydes and N-sulfonyl imines. The most notable progress is the developmentof the asymmetric addition affording the corresponding optically active 1,4-addition product effectively. In this paper, we will summarize the most recent progress in the Rh-, Ni- and Pd-catalyzed 1,4- or 1,2-additions of organoboronicacids.

Key words: metal-catalyzed, addition reaction, organoboronic acid, asymmetric, arylation