Chinese Journal of Organic Chemistry ›› 2023, Vol. 43 ›› Issue (7): 2476-2483.DOI: 10.6023/cjoc202211015 Previous Articles Next Articles
ARTICLES
收稿日期:
2022-11-11
修回日期:
2023-01-25
发布日期:
2023-03-23
通讯作者:
罗书平
基金资助:
Yaxin Liu, Yu Zhang, Shuping Luo()
Received:
2022-11-11
Revised:
2023-01-25
Published:
2023-03-23
Contact:
Shuping Luo
Supported by:
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Yaxin Liu, Yu Zhang, Shuping Luo. Design and Synthesis of Thermal Delayed Fluorescence (TADF) Photocatalyst and Its Photocatalytic Dehalogenation Performance[J]. Chinese Journal of Organic Chemistry, 2023, 43(7): 2476-2483.
Entry | Photocatalyst | Solvent | RSH or RSSR | Additive | Yield/%b |
---|---|---|---|---|---|
1 | 3CzDMAPN | DMSO | (PhS)2 | None | 12 |
2 | 3CzDMAPN | DMSO | (PhS)2 | AcONa | 38 |
3 | 3CzDMAPN | DMSO | (PhS)2 | DIPEA | 46 |
4 | 3CzDMAPN | DMSO | (PhS)2 | HCOOK | 74 |
5 | 3CzDMAPN | DMSO | (PhS)2 | Cs2CO3 | n.d. |
6 | 3CzDMAPN | DMSO | (PhS)2 | Na2CO3 | n.d. |
7 | 3CzDMAPN | DMSO | (PhS)2 | K3PO4 | 0.5 |
8 | 3CzDMAPN | DMSO | (PhS)2 | HCOONa | 77 |
9 | 3CzDMAIPN | DMAc | (PrS)2 | HCOONa | 71 |
10 | 3CzDMATPN | DMAc | (PrS)2 | HCOONa | 74 |
11 | 4CzIPN | DMAc | (PrS)2 | HCOONa | 53 |
12 | 4DPAIPN | DMAc | (PrS)2 | HCOONa | 47 |
13 | 5CzBN | DMAc | (PrS)2 | HCOONa | n.d. |
14 | 3CzDMAPN | DMF | (PhS)2 | HCOONa | 68 |
15 | 3CzDMAPN | DMAc | (PhS)2 | HCOONa | 83 |
16 | 3CzDMAPN | CH3CN | (PhS)2 | HCOONa | 56 |
17 | 3CzDMAPN | NMP | (PhS)2 | HCOONa | 76 |
18 | 3CzDMAPN | EtOAc | (PhS)2 | HCOONa | 49 |
19 | 3CzDMAPN | DMAc | (nPrS)2 | HCOONa | 93 |
20 | 3CzDMAPN | DMAc | (iPrS)2 | HCOONa | 84 |
21 | 3CzDMAPN | DMAc | (CyS)2 | HCOONa | 62 |
22 | 3CzDMAPN | DMAc | (tBuS)2 | HCOONa | 65 |
23 | 3CzDMAPN | DMAc | Triisopropylsilanethiol | HCOONa | 59 |
24 | 3CzDMAPN | DMAc | 2,4,6-Triisopropylbenzenethiol | HCOONa | 52 |
Entry | Photocatalyst | Solvent | RSH or RSSR | Additive | Yield/%b |
---|---|---|---|---|---|
1 | 3CzDMAPN | DMSO | (PhS)2 | None | 12 |
2 | 3CzDMAPN | DMSO | (PhS)2 | AcONa | 38 |
3 | 3CzDMAPN | DMSO | (PhS)2 | DIPEA | 46 |
4 | 3CzDMAPN | DMSO | (PhS)2 | HCOOK | 74 |
5 | 3CzDMAPN | DMSO | (PhS)2 | Cs2CO3 | n.d. |
6 | 3CzDMAPN | DMSO | (PhS)2 | Na2CO3 | n.d. |
7 | 3CzDMAPN | DMSO | (PhS)2 | K3PO4 | 0.5 |
8 | 3CzDMAPN | DMSO | (PhS)2 | HCOONa | 77 |
9 | 3CzDMAIPN | DMAc | (PrS)2 | HCOONa | 71 |
10 | 3CzDMATPN | DMAc | (PrS)2 | HCOONa | 74 |
11 | 4CzIPN | DMAc | (PrS)2 | HCOONa | 53 |
12 | 4DPAIPN | DMAc | (PrS)2 | HCOONa | 47 |
13 | 5CzBN | DMAc | (PrS)2 | HCOONa | n.d. |
14 | 3CzDMAPN | DMF | (PhS)2 | HCOONa | 68 |
15 | 3CzDMAPN | DMAc | (PhS)2 | HCOONa | 83 |
16 | 3CzDMAPN | CH3CN | (PhS)2 | HCOONa | 56 |
17 | 3CzDMAPN | NMP | (PhS)2 | HCOONa | 76 |
18 | 3CzDMAPN | EtOAc | (PhS)2 | HCOONa | 49 |
19 | 3CzDMAPN | DMAc | (nPrS)2 | HCOONa | 93 |
20 | 3CzDMAPN | DMAc | (iPrS)2 | HCOONa | 84 |
21 | 3CzDMAPN | DMAc | (CyS)2 | HCOONa | 62 |
22 | 3CzDMAPN | DMAc | (tBuS)2 | HCOONa | 65 |
23 | 3CzDMAPN | DMAc | Triisopropylsilanethiol | HCOONa | 59 |
24 | 3CzDMAPN | DMAc | 2,4,6-Triisopropylbenzenethiol | HCOONa | 52 |
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