Progress in Porous Organic Polymer for Chemical Fixation of Carnbon Dioxide

doi:10.6023/cjoc202212026

Abstract

Porous organic polymers (POPs) are a new class of porous materials that connect organic structural units by covalent bonds, having the features of various synthetic methods, adjustable pore properties, stable pore structures, low relative density and large specific surface areas. POPs have been applied in fields of gas adsorptions, separations and storage, optoelectronic devices, sensing and heterogeneous catalysis, showing the important application value. Carbon capture, utilization and storage (CCUS) technology is the unique way to significantly reduce carbon dioxide (CO₂) emissions from fossil fuels, and catalytic conversion of CO₂ into valuable fuels or industrial value-added products is an effective and potential strategy to solve the utilization of renewable energy and realize the development of green chemistry. In this review, the synthesis and properties of covalent-organic frameworks (COFs), covalent triazine frameworks (CTFs), hypercrosslinked polymers (HCPs), conjugated microporous polymers (CMPs) and polymer of intrinsic microporosity (PIMs) and their progress of chemical fixation of CO₂ in recent years, is reviewed, and the application prospects of POPs in CO₂ catalysis are prospected.

Key words: porous organic polymers, heterogeneous catalysis, chemical fixation, carbon dioxide conversion, industrial value-added products

Cite this article

Xu Liao, Zeyu Wang, Wufei Tang, Jinqing Lin. Progress in Porous Organic Polymer for Chemical Fixation of Carnbon Dioxide[J]. Chinese Journal of Organic Chemistry, 2023, 43(8): 2699-2710.

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Fig. & Tab. 13

Scheme 1. Types of porous organic polymer frameworks and their coupling chemistries

Scheme 2. Classic reactions used for the construction of COFs

Scheme 3. Synthesis of various cyclic carbonates and oxazolidinones from CO2 catalyzed 2,3-DhaTph COF

Scheme 4. (a) Synthesis of 2-oxazolidinones from CO2 with propargyl amine catalyzed Cu-NPs@COF; (b) synthesis of 2-oxazolidinones from CO2 with propargyl amine catalyzed AgN@COF

Scheme 5. Hierarchical reduction of CO2 with amine to afford formamide, aminal and methylamine catalyzed [BE]x%-TDCOFs

Scheme 6. (a) Synthesis of carbamate from CO2, aniline and 1-bromobutane catalyzed Zn(II)@TFP-DAQ COF; (b) synthesis of carbamate from CO2, benzylamine and methanol catalyzed Ag/TFPG-DMB COF

Scheme 7. Synthesis of tetramic acids by Ag@TpPa-1 catalyzed cyclization of CO2 with propargylic amine derivatives

Scheme 8. Cyclization of CO2 with propargyl alcohols catalyzed Ag@COF

Scheme 9. (a) Cycloaddition of CO2 with epoxides catalyzed CTF-P-HAS; (b) two-step cycloaddition/transesterification of epoxides catalyzed CTF-P-HAS

Scheme 10. Synthesis of various alkynyl carboxylic acids from terminal alkynes with CO2 catalyzed Ag0@CTFN, Ag/PCNF-700 and Ag@p-CTF-250

Scheme 11. Cyclization of CO2 with propargyl alcohols catalyzed Cu(I)@bipy-CTF

Scheme 12. Cycloaddition reaction of CO2 with epoxides catalyzed [HCP-CH2-Im][Cl]-1 and HIP-Cl(3)-OH

Scheme 13. Synthesis of various alkynyl carboxylic acids from terminal alkynes with CO2 catalyzed Ag-HMP-2

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