化学学报 ›› 2003, Vol. 61 ›› Issue (9): 1369-1374. 上一篇    下一篇

研究论文

TiO_2-K_2SiO_3无机涂层对空间材料Ag的防护行为研究

张蕾;严川伟;屈庆;童静宇;曹楚南   

  1. 中国科学院金属研究所;北京卫星环境工程研究所
  • 发布日期:2003-09-15

Study on the Protection of TiO_2-K-2SiO_3 Inorganic Coatings for Ag Used in Space

Zhang Lei;Yan Chuanwei;Qu Qing;Tong Jingyu;Cao Chunnan   

  1. State Key Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences;Beijing Institute of Spacecraft Environment Engineering
  • Published:2003-09-15

在微波电离型原子氮(AO)源地面模拟设备中对空间材料Ag及TiO_2- K_2SiO_3无机涂层进行原子氧剥蚀效应试验。用扫描电镜(SEM)、光电子能谱( XPS)、红外光谱(FT-IR)、X射线衍射光谱(XRD)和LAMBDA-9分光光度计,对在 模拟原子氧(AO)环境中Ag及在其表面涂覆的无机涂层,所发生的侵蚀与防护作用 进行了表征研究。AO对Ag表现了较严重的侵蚀作用,原来光亮如镜的表面形貌变得 粗糙,且失去光泽。而所施用的TiO_2-K_2SiO_3无机涂层,经AO辐照后,表面形貌 则变化甚少。实验表明,该涂层对AO辐照有较强的防护效果、较好的空间稳定性( AO辐照前后Δα ≈ 0.024),能阻止AO对基材的侵蚀。

关键词: 氧化钛, 硅酸钾, 氧, 稳定性, 扫描电子显微镜, X射线光电子谱法, 红外分光光度法, X射线衍射分析

TiO_2-K-2SiO_3 inorganic coatings were prepared and the factors that influenced their properties were described accordingly. The experiments to assess the properties of TiO_2-K-2SiO_3 coatings on silver (Ag has many applications in aerospace technology as solar cell interconnects) for anti-AO effects were carried out and the coatings with and without exposure to AO impingement from ground-simulation were also studied. Fourier transform infrared spectroscopy ( FT-IR), X- ray photoelectron spectroscopy ( XPS), X-ray diffraction ( XRD ), LAMBDA-9 spectrophotometer, and scanning electron microscopy (SEM) were used to characterize the chemical and physical changes of the surfaces of unprotected and protected Ag samples. The results indicate that Ag is susceptible to AO erosion, presents mass loss and surface degraeation. TiO_2-K-2SiO_3 inorganic coatings have excellent properties for anti-AO effects and good stablility for space environment.

Key words: TITANIUM OXIDE, POTASSIUM SILICATE, OXYGEN, STABILITY, SEM, XRD, IR, XRD

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