Research on the Phase Transition and Morphological Evolution Behaviors of Titania/Titanate Nanomaterials by Calcination Treatment

doi:10.6023/A12090724

Acta Chimica Sinica ›› 2013, Vol. 71 ›› Issue (01): 93-101.DOI: 10.6023/A12090724 Previous Articles Next Articles

Article

焙烧处理下二氧化钛/钛酸盐纳米材料晶型和形貌的变化规律研究

赵斌^a, 林琳^a, 陈超^a, 柴瑜超^b, 何丹农^a,b

a 纳米技术及应用国家工程研究中心上海 200241;
b 上海交通大学材料科学与工程学院上海 200240

投稿日期:2012-09-27 发布日期:2012-12-10
通讯作者: 赵斌 E-mail:zhaobinwily@hotmail.com
基金资助:
项目受上海市国际科技合作基金(No. 11520706100)、上海市青年科技启明星计划(B类)(No. 12QB1402800)、国家自然科学基金(No. 21071098)以及国家国际科技合作项目(No. 2011DFA50530)资助.

Research on the Phase Transition and Morphological Evolution Behaviors of Titania/Titanate Nanomaterials by Calcination Treatment

Zhao Bin^a, Lin Lin^a, Chen Chao^a, Chai Yuchao^b, He Dannong^a,b

a National Engineering Research Center for Nanotechnology, Shanghai 200241;
b School of Material Science and Engineering, Shanghai JiaoTong University, Shanghai 200240

Received:2012-09-27 Published:2012-12-10
Supported by:
Project supported by the Shanghai International Science and Technology Cooperation Project (No. 11520706100), Shanghai Rising-Star Program (B-type) (No. 12QB1402800), National Natural Science Foundation of China (No. 21071098) and International Science and Technology Cooperation Project of China (No. 2011DFA50530).

1. Research on the Phase Transition and Morphological Evolution Behaviors of Titania/Titanate Nanomaterials by Calcination Treatment.PDF(175KB)

Abstract

Titania/titanate nanomaterials including rutile, anatase, brookite TiO₂ and sodium dititanate and trititanate were obtained by regulating the acid/alkali concentration under hydrothermal treatment. A systematical investigation was established to uncover the phase transition and morphological evolution behaviors of TiO₂/titanate nanomaterials by calcining the samples including rutile TiO₂ nanorods, anatase TiO₂ nanocrystallines, brookite TiO₂ nanoflowers, acid washed dititanate H₂Ti₂O₅ nanosheets and trititanate H₂Ti₃O₇ nanowires at 400, 600, 800 or 1000 ℃ for 4 h in air with the heating rate of 2 ℃/min. After heat-treatment, the products were taken out from the oven and cooled down to the room temperature. Rietveld refinements of the powder X-ray diffraction (XRD) pattern were used to generally assess the phase composition of the different samples and their crystallite sizes, and to further investigate the phase transition behavior in company with the synthetic parameters. FESEM, TEM, and HRTEM were used to characterize the morphology evolution and to further elucidate the morphological evolution of the resulting products. The crystalline phase distributed diagram of TiO₂/titanate nanostructures dominated by the two experimental parameters indcluding acid/alkali concentration and calcination temperature was presented in the current work based on our experimental results, in which revealed the 5 types of phase transition and morphological evolution behaviors of titania/titanate nanomaterials. 1. Rutile nanorods → rutile nanorod aggregations → rutile micro particles. 2. Anatase nanocrystallines → anatase nanoparticle aggregations → rutile micro particles. 3. Brookite nano- flowers → brookite nanoflower clusters → rutile micro clusters. 4. Dititanate H₂Ti₂O₅ nanosheets →anatase nanoparticle aggregations → rutile micro clusters. 5. Trititanate H₂Ti₃O₇ nanowires → TiO₂-B nanowires → anatase nanowire aggregations → rutile micro clusters. The crystal growth and phase transition mechanism was discussed based on the Ostwald’s step rule. Moreover, morphological evolution mechanism was also discussed based on the thermodynamic equilibrium regime and oriented attachment growth model.

Key words: titania, titanate, calcinations, phase transition, morphological evolution, mechanism

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Zhao Bin, Lin Lin, Chen Chao, Chai Yuchao, He Dannong. Research on the Phase Transition and Morphological Evolution Behaviors of Titania/Titanate Nanomaterials by Calcination Treatment[J]. Acta Chimica Sinica, 2013, 71(01): 93-101.

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焙烧处理下二氧化钛/钛酸盐纳米材料晶型和形貌的变化规律研究

Research on the Phase Transition and Morphological Evolution Behaviors of Titania/Titanate Nanomaterials by Calcination Treatment

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