Acta Chimica Sinica ›› 2002, Vol. 60 ›› Issue (7): 1346-1349. Previous Articles     Next Articles

Original Articles

多孔玻璃粉在蒸汽相中自转晶合成含硼CF-2沸石

董维阳;任瑜;邱锡鹏;周伟正;龙英才   

  1. 复旦大学化学系分子催化与创新材料实验室.上海(200433);复旦大学计算机 科学与工程系.上海(200433)
  • 发布日期:2002-07-15

Synthesis of Boron-containing CF-2 Zeolite by Self-transformation of Proous Glass Granules in a Vapor Phase

Dong Weiyang;Ren Yu;Qiu Xipeng;Zhou Weizheng;Long Yingcai   

  1. Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University.Shanghai(200433);Department of Computer Science and Engineering, Fudan University.Shanghai(200433)
  • Published:2002-07-15

Boron-containing CF-2 zeolite with high crystallinity and purity, which is first reported, was synthesized by self-transformation of porous glass granules in the vapor phase of methylamine and water. ~ (11)B MAS NMR spectra prove that the atoms of B in the raw glass have been essentially completely incorporated into the zeolite framework. The as-synthesized crystals of CF-2 zeolite are rectangular rod-shaped. Some of the crystals are individuals and the others are aggregates.

Key words: ZEOLITE, XRD, METHANAMINE, WATER, SEM, AGGREGALES

CLC Number: