Oxidation of alkylanthracene

Abstract

Oxidation of 9-alkylanthracene by pyridine-iodine proceeded mainly through nucleophilic attack of the solvent molecule on the intermediate radical cation. In the case of 9,10-dialkylanthracene, deprotonation leading to side-chain oxidation was sole procedure, and deprotonation of methyl was much more rapid than that of ethyl and cyclopylanthracene.

Key words: ULTRAVIOLET SPECTROPHOTOMETRY, OXIDATION, REACTION MECHANISM, INFRARED SPECTROPHOTOMETRY, ELEMENTAL ANALYSIS, PYRIDINE, PROTON MAGNETIC RESONANCE SPECTROMETRY, ANTHRACENE P, TRICHLOROMETHANE

CLC Number:

O621

Cite this article

LI ZAOZAO;L.M.TOLBERT. Oxidation of alkylanthracene[J]. Acta Chimica Sinica, 1995, 53(12): 1204-1208.

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烷基取代蒽的单电子氧化

Oxidation of alkylanthracene

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