The determination of the most probable mechanism functions and kinetic parameters of the thermal decomposition reaction of complexes of rare earth isothiocyanates with benzylamine by non-isothermal DSC curves

Acta Chimica Sinica ›› 1991, Vol. 49 ›› Issue (6): 521-523. Next Articles

Original Articles

用非等温DSC曲线确定Ln(NCS)3-·4C3H5CH2NH2的热分解反应机理函数及热分解反应动力学参数

杨淑荣;张建华;蒋本杲;杨兆荷

山东大学化学学院;山东大学晶体材料研究所

发布日期:1991-06-15

The determination of the most probable mechanism functions and kinetic parameters of the thermal decomposition reaction of complexes of rare earth isothiocyanates with benzylamine by non-isothermal DSC curves

YANG SHURONG;ZHANG JIANHUA;JIANG BENGAO;YANG ZHAOHE

Published:1991-06-15

Abstract

The thermal decomposition of the complexes Ln(NCS)34C6H5CH2NH2 (Ln = La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, and Yb) was studied under non-isothermal condition by DSC curves. Kinetic parameters were obtained from anal. of the DSC curves by the integral and differential methods. Their kinetic equations may be expressed as: da/dt = Ae-E/RT(3(1-a)2/3) when Ln = La, Pr, Nd, Sm, Eu, Gd and da/dt = Ae-E/RT((1-a) when Ln = Tb, Dy, Ho, Er, Tm, Yb. The math. expression of the kinetic compensation effect of these thermal decomposition reactions was obtained. Possible mechanisms are suggested.

Key words: REACTION MECHANISM, DIFFERENTIATION, KINETICS EQUATIONS, HOLMIUM COMPLEX, DIFFERENTIAL SCANNING CALORIMETRY, ISOTHIOCYANATE, YTTERBIUM COMPLEX, PRASEODYMIUM COMPLEX, EUROPIUM COMPLEX, LANTHANUM COMPLEX

CLC Number:

Cite this article

YANG SHURONG;ZHANG JIANHUA;JIANG BENGAO;YANG ZHAOHE. The determination of the most probable mechanism functions and kinetic parameters of the thermal decomposition reaction of complexes of rare earth isothiocyanates with benzylamine by non-isothermal DSC curves[J]. Acta Chimica Sinica, 1991, 49(6): 521-523.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Guanglong Huang, Xiao-Song Xue. Computational Study on the Mechanism of Chen’s Reagent as Trifluoromethyl Source [J]. Acta Chimica Sinica, 2024, 82(2): 132-137.
[2]	Guoqing Cui, Yiyang Hu, Yingjie Lou, Mingxia Zhou, Yuming Li, Yajun Wang, Guiyuan Jiang, Chunming Xu. Research Progress on the Design, Preparation and Properties of Catalysts for CO₂ Hydrogenation to Alcohols [J]. Acta Chimica Sinica, 2023, 81(8): 1081-1100.
[3]	Xinpu Fu, Xiuling Wang, Weiwei Wang, Rui Si, Chunjiang Jia. Fabrication and Mechanism Study of Clustered Au/CeO₂ Catalyst for the CO Oxidation Reaction^★ [J]. Acta Chimica Sinica, 2023, 81(8): 874-883.
[4]	Luocong Wang, Zhewei Li, Caiwei Yue, Peihuan Zhang, Ming Lei, Min Pu. Theoretical Study on the Isomerization Mechanism of Azobenzene Derivatives under Electric Field [J]. Acta Chimica Sinica, 2022, 80(6): 781-787.
[5]	Siming Yang, Airong Liu, Jing Liu, Zhaoli Liu, Weixian Zhang. Advance of Sulfidated Nanoscale Zero-Valent Iron: Synthesis, Properties and Environmental Application [J]. Acta Chimica Sinica, 2022, 80(11): 1536-1554.
[6]	Yilong Hua, Donghan Li, Tianhang Gu, Wei Wang, Ruofan Li, Jianping Yang, Wei-xian Zhang. Enrichment of Uranium from Aqueous Solutions with Nanoscale Zero-valent Iron: Surface Chemistry and Application Prospect [J]. Acta Chimica Sinica, 2021, 79(8): 1008-1022.
[7]	Huang Rongyi, Shen Qiong, Zhang Chao, Zhang Shaoyong, Xu Heng. Studies on the Mechanism of the Transition Metal-Catalyzed Reaction of Organonitrile with Sodium Azide [J]. Acta Chimica Sinica, 2020, 78(6): 565-571.
[8]	Wu Weirong, Yuan Xiaomin, Hou Hua, Wang Baoshan. Theoretical Investigations on the Mechanisms for the Reactions of Sevoflurane Radicals[(CF₃)₂C(·)OCH₂F, (CF₃)₂CHOC(·)HF] with O₂and the OH· Radicals Regeneration [J]. Acta Chim. Sinica, 2018, 76(10): 793-801.
[9]	Mu Weihua, Ma Yao, Fang Decai, Wang Rong, Zhang Haina. Computational Insights into the Diels-Alder-alike Reactions of 1-Iodo-2-Lithio-o-Carborane with Fulvenes [J]. Acta Chim. Sinica, 2018, 76(1): 55-61.
[10]	Huang Xiao-yue, Wang Wei, Ling Lan, Zhang Wei-xian. Heavy Metal-nZVI Reactions: the Core-shell Structure and Applications for Heavy Metal Treatment [J]. Acta Chim. Sinica, 2017, 75(6): 529-537.
[11]	Tang Jing, Tang Lin, Feng Haopeng, Dong Haoran, Zhang Yi, Liu Sishi, Zeng Guangming. Research Progress of Aqueous Pollutants Removal by Sulfidated Nanoscale Zero-valent Iron [J]. Acta Chim. Sinica, 2017, 75(6): 575-582.
[12]	Ding Shuang, Ge Qingfeng, Zhu Xinli. Research Progress in Ketonization of Biomass-derived Carboxylic Acids over Metal Oxides [J]. Acta Chim. Sinica, 2017, 75(5): 439-447.
[13]	Yang Zhen, Xue Yijiang, He Yuanhang. Thermal Sensitivity of CL20/DNB Co-crystal Research via Molecular Dynamics Simulations [J]. Acta Chim. Sinica, 2016, 74(7): 612-619.
[14]	Ma Jun, Li Rong, Ren Kuiwei, Ma Xilong, Zhu Kaili, Geng Zhiyuan. Mechanism and Spin-orbit Coupling Study for Two State Reaction Ni₂⁺ with Cyclohexane [J]. Acta Chim. Sinica, 2015, 73(5): 431-440.
[15]	Wang Ying, Zhang Limin, Hu Tianjun. Progress in Oxygen Reduction Reaction Electrocatalysts for Metal-Air Batteries [J]. Acta Chim. Sinica, 2015, 73(4): 316-325.

用非等温DSC曲线确定Ln(NCS)3-·4C3H5CH2NH2的热分解反应机理函数及热分解反应动力学参数

The determination of the most probable mechanism functions and kinetic parameters of the thermal decomposition reaction of complexes of rare earth isothiocyanates with benzylamine by non-isothermal DSC curves

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments