Acta Chimica Sinica ›› 1998, Vol. 56 ›› Issue (10): 973-978. Previous Articles     Next Articles

Original Articles

DL-苹果酸-丙酮-BrO~3^--Mn^2^+-H~2SO~4化学振荡 反应诱导期的新特征 及其动力学研究

安从俊;甘南琴;刘义;李俊峰;林智信   

  1. 武汉大学化学系.武汉(430072)
  • 发布日期:1998-10-15

New characteristics of the inductory phase and kinetic study of DL- malic acid-acetone-BrO~3^--Mn^2^+-H~2SO~4 chemical oscillatory reaction

An Congjun;Gan Nanqin;Liu Yi;Li Junfeng;Lin Zhixin   

  1. Wuhan Univ, Dept Chem.Wuhan(430072)
  • Published:1998-10-15

As an extension of our previous study, this paper reports a new type of oscillatory reaction system: DL-malic acid (abbreviated to DL-MA)- CH~3COCH~3 (abbreviated to Act)-Mn^2^+-H~2SO~4, and all factors that affect the reaction. The role of each reactant in the inductory phase, the cause of oscillation, the new characteristics of the inductory phase and possible mechanism of oscillatory reaction have been investigated. The simulation equations in which the inductory phase is affected by concentration of DL-MA, KBrO~3 and MnSO~4 are obtained. The activation parameter of the inductory phase, E~I~N is 68.50kJ· mol^-^1.

Key words: OSCILLATION CHEMICAL REACTION, INCUBATION PERIOD, MALIC ACID, ACETONE, REACTION MECHANISM, KINETIC STUDY

CLC Number: