有机化学 ›› 2017, Vol. 37 ›› Issue (1): 31-39.DOI: 10.6023/cjoc201607003 上一篇    下一篇

综述与进展

过渡金属催化偶氮基导向的C(sp2)-H键官能团化研究进展

黄房生a,b, 陈训a, 谢应a, 曾伟a   

  1. a 华南理工大学化学与化工学院 广州 510640;
    b 英德市良仕工业材料有限公司 清远 513059
  • 收稿日期:2016-07-02 修回日期:2016-08-19 出版日期:2017-01-25 发布日期:2016-09-06
  • 通讯作者: 曾伟 E-mail:zengwei@scut.edu.cn
  • 基金资助:

    国家自然科学基金(No. 21372085)、广州市科技计划项目(No.156300075)和清远市科技计划(No.2014D006)资助项目.

Progress in the Transition Metal-Catalyzed C(sp2)-H Bond Functionalization of Azoarenes

Huang Fangshenga,b, Chen Xuna, Xie Yinga, Zeng Weia   

  1. a School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640;
    b Yingde Liangshi Industrial Material Co. Ltd, Qingyuan 513059
  • Received:2016-07-02 Revised:2016-08-19 Online:2017-01-25 Published:2016-09-06
  • Supported by:

    Project supported by the National Natural Science Foundation of China(No. 21372085), the Science and Technology Program of Guangzhou City(No. 156300075) and the Science and Technology Program of Qingyuan(No.2014D006).

芳香偶氮化合物在有机染料、医药、蛋白探针和功能材料等领域应用广泛,高效构建偶氮功能化的芳烃衍生物是有机合成化学的研究热点领域之一.过渡金属催化偶氮基导向C(sp2)-H键官能团化策略因可高区域选择性和高原子经济性地构建多样性芳基偶氮化合物而备受关注.对近年来过渡金属催化偶氮功能基导向的C-H键官能团化反应类型及相关反应机理予以论述,为后续研究提供参考.

关键词: 芳基偶氮化合物, 过渡金属催化, C(sp2)-H键官能化反应, 导向功能基

Developing simple and concise methods to construct azoarene derivatives has aroused wide concerns due to that these compounds are widely used in the fields of organic dyes,medicines,protein probe and functional materials.As a highly atom- and step-economical approach to making these compounds,transition metal-catalyzed azo group-directed C(sp2)-H bond functionalization provides an efficient synthetic method to regioselectively assemble azoarenes.The reaction types about diverse C(sp2)-H bond functionalzation of azoarenes were summarized in this paper.

Key words: azoarenes, transition metal catalysis, C(sp2)-H bond functionalization, directing groups