有机化学 ›› 2018, Vol. 38 ›› Issue (10): 2571-2589.DOI: 10.6023/cjoc201803045 上一篇    下一篇

所属专题: 元素有机化学合辑2018-2019 有机氟化学合辑

综述与进展

过渡金属促进三氟甲基化反应的研究进展

陈董涵, 杨文, 姚永祺, 杨新, 邓颖颍, 杨定乔   

  1. 华南师范大学化学与环境学院 教育部环境理论化学重点实验室 广州 510006
  • 收稿日期:2018-03-27 修回日期:2018-05-15 发布日期:2018-06-06
  • 通讯作者: 杨定乔,E-mail:yangdq@scnu.edu.cn E-mail:yangdq@scnu.edu.cn
  • 基金资助:

    国家自然科学基金(Nos.21172081,21372090)、广东省自然科学基金重点(No.S2013020013091)和广州市科技计划(No.201510010054)资助项目.

Recent Advances in Transition Metal-Promoted Trifluoromethylation Reactions

Chen Donghan, Yang Wen, Yao Yongqi, Yang Xin, Deng Yingying, Yang Dingqiao   

  1. Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, School of Chemistry and Environment, South China Normal University, Guangzhou 510006
  • Received:2018-03-27 Revised:2018-05-15 Published:2018-06-06
  • Contact: 10.6023/cjoc201803045 E-mail:yangdq@scnu.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21172081, 21372090), the Natural Science Foundation of Guangdong Province (No. S2013020013091) and the City of Guangzhou Science and Technology Plan Projects (No. 201510010054).

近年来,过渡金属促进三氟甲基化反应得到了快速发展.从促进三氟甲基化反应的过渡金属种类出发,综述了近几年来银、铁、钯、镍、铑和钴促进三氟甲基化反应的研究进展,并对部分反应可能的机理进行了讨论.

关键词: 过渡金属, 三氟甲基化, 研究进展

Recently, transition metal-promoted trifluoromethylation has been developed rapidly. Starting with the types of transition metal that promote the trifluoromethylation reactions, the research progress of trifluoromethylation promoted by silver, iron, palladium, nickel, rhodium and cobalt in recent years is reviewed. Moreover, the possible mechanisms of some parts of reactions are also discussed.

Key words: transition metal, trifluoromethylation, research progress