有机化学 ›› 2019, Vol. 39 ›› Issue (11): 3065-3083.DOI: 10.6023/cjoc201905016 上一篇    下一篇

所属专题: 碳氢活化合辑2018-2019 有机光催化合辑

综述与进展

可见光诱导的无过渡金属催化交叉脱氢偶联反应研究进展

孔瑶蕾, 徐雯秀, 叶飞霞, 翁建全*()   

  1. 浙江工业大学化学工程学院 杭州 310014
  • 收稿日期:2019-05-09 发布日期:2019-07-09
  • 通讯作者: 翁建全 E-mail:jqweng@zjut.edu.cn
  • 基金资助:
    浙江省自然科学基金(LY17C140003)

Recent Advances in Visible-Light-Induced Cross Dehydrogenation Coupling Reaction under Transition Metal-Free Conditions

Kong Yaolei, Xu Wenxiu, Ye Feixia, Weng Jianquan*()   

  1. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014
  • Received:2019-05-09 Published:2019-07-09
  • Contact: Weng Jianquan E-mail:jqweng@zjut.edu.cn
  • Supported by:
    the Natural Science Foundation of Zhejiang Province(LY17C140003)

交叉脱氢偶联反应通过两种不同的X-H键直接偶联生成新的化学键,具有优异的步骤经济性和原子经济性.传统交叉脱氢偶联反应通常以过渡金属催化,存在催化剂昂贵及污染严重等问题.可见光诱导电子转移也是实现X-H键直接官能化的有效途径.可见光诱导的无过渡金属催化交叉脱氢偶联反应因具有清洁安全、步骤和原子经济性高等优点从而受到广泛关注.根据成键类型分类,综述了该类反应的研究进展,并对其前景进行了展望.

关键词: 交叉脱氢偶联, 可见光诱导, 无过渡金属, 官能化

The cross dehydrogenation coupling reaction realizes direct coupling of two different X-H bonds to form a new chemical bond, thus featuring excellent step and atom economy. The traditional cross dehydrogenation coupling reaction was usually catalyzed by transition metal, which had the problems of expensive catalyst and serious pollution. Visible light-induced electron transfer is also an effective way to realize direct functionalization of X-H bonds. Visible-light-induced cross dehydrogenation coupling reaction under transition metal-free conditions is widely concerned due to the advantages of cleanliness, safety as well as high step and atom economy. Classified by the type of bonding, the research progress of these reactions is reviewed, and their future outlook is also discussed.

Key words: cross dehydrogenation coupling, visible-light-induced, transition metal-free, functionalization