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有机化学
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有机化学 ›› 2005, Vol. 25 ›› Issue (05): 496-506. 上一篇    下一篇

综述与进展

金属催化硫醚的不对称氧化研究进展

黄秋亚，朱槿*，邓金根*   

  1. (中国科学院成都有机化学研究所 手性技术与不对称合成四川省重点实验室
    不对称联合开放实验室 成都610041)
  • 收稿日期:2004-04-30 修回日期:2004-11-01 发布日期:2004-04-30
  • 通讯作者: 朱槿

Recent Development in Asymmetric Catalytic Oxidation of Prochiral Sulfides by Metal-based Catalysts

HUANG Qiu-Ya,ZHU Jin*,DENG Jin-Gen*   

  1. (Key Laboratory of Asymmetric Synthesis & Chirotechnology of Sichuan Province, Union Laboratory of Asym-metric
    Synthesis, Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041)
  • Received:2004-04-30 Revised:2004-11-01 Published:2004-04-30
  • Contact: ZHU Jin

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3422

被引次数

39

手性金属络合物催化硫醚的不对称氧化是合成手性亚砜最有效的方法. 理性设计各种手性金属络合物催化剂应用于催化对映选择性氧化潜手性硫醚反应中, 近年来引起了化学家们较大的关注. 综述了各类手性金属络合物催化剂在硫醚不对称氧化中的应用.

关键词: 不对称氧化, 手性金属络合物, 硫醚, 手性亚砜

The most efficient way to generate chiral sulfoxides is asymmetric oxidation of prochiral sulfides catalyzed by chiral metal complexes. Recently, the rational design of chiral metal complexes for enantiomerically catalytic oxidation of sulfides attracts much attention. Applications of a variety of metal-based catalysts to asymmetric oxidation of sulfides were reviewed.

Key words: chiral metal complex, chiral sulfoxide, asymmetric oxidation, sulfide