有机化学 ›› 2010, Vol. 30 ›› Issue (02): 211-219. 上一篇    下一篇

综述与进展

非膦配体Pd催化的偶联反应发展进程

许华建1,2,汤琳1,张博1,郑法银1,冯乙巳*,1,2   

  1. (1合肥工业大学化学工程学院 合肥 230009)
    (2可控化学与材料化工安徽省重点实验室 合肥 230009)
  • 收稿日期:2009-05-05 修回日期:2009-06-09 发布日期:2010-02-20

Recent Progress in Palladium Catalyzed Coupling Reactions Medi-ated by Phosphine-Free Ligands

Xu Huajian1,2 Tang Lin1 Zhang Bo1 Zheng Fayin1 Feng Yisi*,1,2   

  1. (1 School of Chemical Engineering, Hefei University of Technology, Hefei 230009)
    (2 Anhui Key Laboratory of Controllable Chemistry Reaction & Material Chemical Engi-neering, Hefei 230009)
  • Received:2009-05-05 Revised:2009-06-09 Published:2010-02-20

膦配体钯催化的偶联反应在工业应用中占据重要地位, 但因传统膦配体的使用有诸多弊端, 因而导致非膦配体的发展及应用. 按照不同类别对非膦配体的新进展进行了综述.

关键词: 钯催化, 偶联反应, 非膦配体, 绿色化学

Palladium-catalyzed coupling reaction plays a important role in industry. Many disadvantages were found using phosphine ligands under traditional conditions. Development and application of phosphine-free ligands have attracted much attention. This review is focused on progress in different kind of phosphine-free ligands recently.

Key words: palladium-catalyzed, coupling reaction, phosphine-free ligand, green chemistry