有机化学 ›› 2013, Vol. 33 ›› Issue (11): 2391-2395.DOI: 10.6023/cjoc201305016 上一篇    下一篇

研究论文

氨功能化的MCM-41催化丙二腈与α,β-不饱和酮的Michael加成

王长春, 谢绍雷, 解正峰, 惠永海   

  1. 石油天然气精细化工教育部 & 新疆维吾尔自治区重点实验室 新疆大学化学化工学院 乌鲁木齐 830046
  • 收稿日期:2013-05-10 修回日期:2013-06-13 出版日期:2013-11-25 发布日期:2013-07-10
  • 通讯作者: 惠永海 E-mail:hyhmsq@gmail.com
  • 基金资助:

    国家自然科学基金(Nos. 21162026,20962018,20862015)资助项目.

Michael Addition Reaction of Malononitrile and α,β-Unsaturated Ketones Catalyzed by Amine Functionalized MCM-41

Wang Changchun, Xie Shaolei, Xie Zhengfeng, Hui Yonghai   

  1. Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education & Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046
  • Received:2013-05-10 Revised:2013-06-13 Online:2013-11-25 Published:2013-07-10
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21162026, 20962018, 20862015).

利用氨功能化的MCM-41催化了丙二腈与αβ-不饱和酮的Michael加成反应,甲醇作溶剂,常温下反应产率高达99%,同时得到了一系列高产率的氰基类衍生物,催化剂具有合成简单、环境友好、多次循环利用等特点.

关键词: 氨功能化MCM-41, α,β-不饱和酮, 丙二腈, 催化, Michael加成

Michael addition reaction of α, β-unsaturated ketones and malononitrile that catalyzed by amine functionalized MCM-41 in methanol afforded a series of cyano derivatives with high yield (up to 99%). The products were afforded at room temperature. Moreover, the catalyst was also found to easiness to handle up, friendly environment, and excellent recyclability.

Key words: amine functionalized MCM-41, α,β-unsaturated ketones, malononitrile, catalysis, Michael addition