有机化学 ›› 2015, Vol. 35 ›› Issue (9): 1834-1847.DOI: 10.6023/cjoc201503040 上一篇    下一篇

综述与进展

螯合型氮杂环卡宾金属化合物的研究进展

杨亮茹, 郭旗, 肖咏梅, 毛璞   

  1. 河南工业大学化学化工学院 郑州 450001
  • 收稿日期:2015-03-25 修回日期:2015-05-22 出版日期:2015-09-25 发布日期:2015-06-04
  • 通讯作者: 杨亮茹, 毛璞 E-mail:lryang@haut.edu.cn;maopu@haut.edu.cn
  • 基金资助:

    国家自然科学基金(No. 21172055)、郑州市科技创新团队(No. 131PCXTD605)和河南工业大学科技创新人才培育计划(No. 11CXRC10)资助项目.

Development of Chelating N-Heterocyclic Carbene Metal Complexes

Yang Liangru, Guo Qi, Xiao Yongmei, Mao Pu   

  1. School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450001
  • Received:2015-03-25 Revised:2015-05-22 Online:2015-09-25 Published:2015-06-04
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21172055), the Program for Innovative Research Team from Zhengzhou (No. 131PCXTD605) and the Plan for Scientific Innovation Talent of Henan University of Technology (No. 11CXRC10).

氮杂环卡宾金属化合物已被广泛应用于有机、材料、医药及生物科学等领域. 从金属化合物的结构出发, 主要介绍含NHC⌒P、NHC⌒N、NHC⌒O和NHC⌒S配体螯合型金属化合物的合成及应用, 综述了近年来基于氮杂环卡宾的螯合型金属化合物合成与应用的最新研究进展.

关键词: 螯合型金属化合物, 氮杂环卡宾, 合成, 应用

N-Heterocyclic carbene (NHC) metal complexes have been widely used in the fields of organic chemistry, material, pharmacy and biology chemistry. The recent progress in the synthesis and application of chelating NHC metal complexes containing different chelating ligands, such as NHC⌒P, NHC⌒N, NHC⌒O and NHC⌒S is summarized.

Key words: chelating metal complexes, N-heterocyclic carbene, synthesis, application