过渡金属催化的基于季铵盐C-N键断裂的偶联反应研究进展

doi:10.6023/cjoc201803013

有机化学 ›› 2018, Vol. 38 ›› Issue (8): 1949-1962.DOI: 10.6023/cjoc201803013 上一篇下一篇

综述与进展

过渡金属催化的基于季铵盐C-N键断裂的偶联反应研究进展

李刚^a,b, 陈烨^a, 夏纪宝^b

a 贵州大学化学与化工学院贵阳 550025;
b 中国科学院兰州化学物理研究所苏州研究院羰基合成与选择氧化国家重点实验室兰州 730000

收稿日期:2018-03-12 修回日期:2018-04-08 发布日期:2018-04-27
通讯作者: 陈烨, 夏纪宝 E-mail:jibaoxia@licp.cas.cn;ychen19@gzu.edu.cn
基金资助:
国家自然科学基金（Nos.21702212，21772208，21402089）和江苏省自然科学基金（No.BK20161260）资助项目.

Progress on Transition-Metal-Catalyzed Cross-Coupling Reactions of Ammonium Salts via C-N Bond Cleavage

Li Gang^a,b, Chen Ye^a, Xia Jibao^b

a School Chemistry of Chemical Engineering, Guizhou University, Guiyang 550025;
b State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics(LICP), Chinese Academy of Sciences, Lanzhou 730000

Received:2018-03-12 Revised:2018-04-08 Published:2018-04-27
Contact: 10.6023/cjoc201803013 E-mail:jibaoxia@licp.cas.cn;ychen19@gzu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21702212, 21772208, 21602230) and the Natural Science Foundation of Jiangsu Province (No. BK20161260).

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摘要/Abstract

含有碳-氮（C-N）键的胺类化合物广泛存在于天然产物、药物分子和功能材料之中.C-N键作为分布最广且相对惰性的化学键之一，通过对其选择性的断裂来构建新的碳-碳（C-C）或碳-杂（C-X）键在近年来逐渐发展为一种新的合成方法.季铵盐化合物易于从胺类化合物合成，发生C-N键断裂相对容易.综述了近年来以季铵盐为原料通过过渡金属催化的C-N键断裂实现的交叉偶联反应.

关键词: 过渡金属催化, 季铵盐, 交叉偶联反应, C-N键断裂

Amines containing carbon-nitrogen (C-N) bonds are widely distributed in natural products, drug molecules and functional materials. C-N bonds are one of the most abundant and inert bonds in organic molecules. Selective cleavage of C-N bonds to construct carbon-carbon (C-C) and carbon-heteroatom (C-X) bonds represents a new synthetic method in organic synthesis. It is difficult for the direct cleavage of C-N bond. Ammonium salts are a series of stable compounds easily obtained from amines. The recent progress of transition-metal-catalyzed cross-coupling reactions via C-N bond cleavage using ammonium salts as starting materials is summerized.

Key words: transition-metal-catalysis, ammonium salt, cross-coupling reaction, C-N bond cleavage

引用此文

李刚, 陈烨, 夏纪宝. 过渡金属催化的基于季铵盐C-N键断裂的偶联反应研究进展[J]. 有机化学, 2018, 38(8): 1949-1962.

Li Gang, Chen Ye, Xia Jibao. Progress on Transition-Metal-Catalyzed Cross-Coupling Reactions of Ammonium Salts via C-N Bond Cleavage[J]. Chin. J. Org. Chem., 2018, 38(8): 1949-1962.

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过渡金属催化的基于季铵盐C-N键断裂的偶联反应研究进展

Progress on Transition-Metal-Catalyzed Cross-Coupling Reactions of Ammonium Salts via C-N Bond Cleavage

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