有机化学 ›› 2019, Vol. 39 ›› Issue (7): 1831-1836.DOI: 10.6023/cjoc201903001 上一篇    下一篇

综述与进展

芳甲基叠氮化合物与烯烃及其衍生物反应研究进展

李秀英a, 李亚军b, 韦贤生a, 罗金荣a, 黄国保a, 谭明雄a   

  1. a 广西农产资源化学与生物技术重点实验室 玉林师范学院化学与食品科学学院 玉林 537000;
    b 湖南环境生物职业技术学院医药技术学院 衡阳 421005
  • 收稿日期:2019-03-01 修回日期:2019-03-30 出版日期:2019-07-25 发布日期:2019-04-16
  • 通讯作者: 黄国保, 谭明雄 E-mail:lzjx0915@163.com;tanmx00@163.com
  • 基金资助:

    国家自然科学基金(No.21761033)、广西自然科学基金(Nos.2017GXNSFBA198211,2018GXNSFAA294064)以及玉林师范学院科研(Nos.2018YJKY36,201810606010)项目资助.

Recent Progress on Reactions of Arylmethyl Azides with Alkenes

Li Xiuyinga, Li Yajunb, Wei Xianshenga, Luo Jinronga, Huang Guobaoa, Tan Minxionga   

  1. a Guangxi Key Laboratory of Agricultural Resources Chemistry and Biotechnology, College of Chemistry and Food Science of Yulin Normal University, Yulin 537000;
    b College of Medicine & Technology, Hunan Polytechnic of Environment and Biology, Hengyang 421005
  • Received:2019-03-01 Revised:2019-03-30 Online:2019-07-25 Published:2019-04-16
  • Contact: 10.6023/cjoc201903001 E-mail:lzjx0915@163.com;tanmx00@163.com
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21761033), the Natural Science Foundation of Guangxi (Nos. 2017GXNSFBA198211, 2018GXNSFAA294064), and the Yulin Normal University Research (Nos. 2018YJKY36, 201810606010).

芳甲基叠氮化合物(ArCH2N3)可以为有机反应提供氮源,是一种性质稳定、合成简单的试剂,在有机合成化学领域被广泛应用.综述了最近五年来芳甲基叠氮化合物与烯烃在有机合成反应中的最新研究进展.分别叙述了芳甲基叠氮化合物在有机反应中与烯烃及其衍生物的底物适应范围和反应机理,为今后芳甲基叠氮化合物与烯烃类化合物的反应在有机合成中的应用提供参考.

关键词: 芳甲基叠氮化合物, 烯烃, 反应机理

Arylmethyl azides (ArCH2N3) as one of the significant nitrogen sources with stable properties, simple synthesis, have been widely used in a wide range of organic synthesis reactions. The recent progress (2014~2018) on reactions of arylmethyl azides with alkenes is summarized. In addition, the organic reactions of arylmethyl azides with types of alkenes are described respectively, with their scope of substrates and reaction mechanism. It is hoped that this review can be referred to the future application in organic synthesis of arylmethyl azides with alkenes.

Key words: arylmethyl azides, alkenes, reaction mechanism