Efficient Synthesis of β-Amino Alcohols Promoted by Triphenylbismuth Bisperfluorooctanesulfonates

doi:10.6023/cjoc201510035

Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (5): 1094-1098.DOI: 10.6023/cjoc201510035 Previous Articles Next Articles

NOTE

三苯基铋全氟辛基磺酸盐催化β-氨基醇高效合成

谭年元^a, 王鹏辉^b, 许新华^b, 高青松^c, 区泽棠^a,b, 邱仁华^b

a. 湖南工程学院化学化工学院湘潭 411104;
b. 湖南大学化学化工学院长沙 410082;
c. 湖北省纤维检验局武汉 430061

收稿日期:2015-10-29 修回日期:2016-01-21 发布日期:2016-01-29
通讯作者: 区泽棠, 邱仁华 E-mail:pctowl@hotmail.com;renhuaqiu@hnu.edu.cn
基金资助:
国家自然科学基金(No.21373003)、湖南省自然科学基金(No.14JJ7027)、湖南省教育厅重点(No.15A041)资助项目.

Efficient Synthesis of β-Amino Alcohols Promoted by Triphenylbismuth Bisperfluorooctanesulfonates

Tan Nianyuan^a, Wang Penghui^b, Xu Xinhua^b, Gao Qingsong^c, Au Chaktong^a,b, Qiu Renhua^b

a. College of Chemistry and Chemical Engineering, Hunan Institute of Engineering, Xiangtan 411104;
b. College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082;
c. Hubei Province Fibre Inspection Bureau, Wuhan 430061

Received:2015-10-29 Revised:2016-01-21 Published:2016-01-29
Supported by:
Projected support by the National Natural Science Foundation of China (No. 21373003), the Natural Science Foundation of Hunan Province (No. 14JJ7027), and the Key Project of Hunan Province Education Department (No. 15A041).

1. Efficient Synthesis of β-Amino Alcohols Promoted by Triphenylbismuth Bisperfluorooctanesulfonates.PDF(2161KB)

Abstract

In this paper, a novel air-stable triphenylbismuth bisperfluorooctanesulfonate was synthesized by treatment of moisture-sensitive triphenylbismuth dichloride with silver bisperfluorooctanesulfonate in anhydrous CH₂Cl₂ at room temperature. Its catalytic assessment results show that the reactions of arylamine and epoxide proceed efficiently in the presence of triphenylbismuth bisperfluorooctanesulfonates 1(5.0 mol%) under solvent-free condition, affording β-amino alcohols in good to excellent yields. The yields of desired products do not reduce obviously after recycling for 4 times of catalyst 1. Hence, a convenient and efficient method for preparation of β-amino alcohols is provided.

Key words: organobismuth, perfluorooctanesulfonate, Lewis acid, β-amino alcohol, solvent-free synthesis

Cite this article

Tan Nianyuan, Wang Penghui, Xu Xinhua, Gao Qingsong, Au Chaktong, Qiu Renhua. Efficient Synthesis of β-Amino Alcohols Promoted by Triphenylbismuth Bisperfluorooctanesulfonates[J]. Chin. J. Org. Chem., 2016, 36(5): 1094-1098.

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三苯基铋全氟辛基磺酸盐催化β-氨基醇高效合成

Efficient Synthesis of β-Amino Alcohols Promoted by Triphenylbismuth Bisperfluorooctanesulfonates

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