Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (4): 802-811.DOI: 10.6023/cjoc201709041 Previous Articles     Next Articles

Reviews

金属钯催化有机铝试剂与亲电试剂的偶联反应研究进展

李清寒, 杓学蓓, 张刚, 丁勇, 杨学军, 陈峰   

  1. 西南民族大学化学与环境保护工程学院 成都 610041
  • 收稿日期:2017-06-25 修回日期:2017-10-23 出版日期:2018-04-24 发布日期:2017-11-15
  • 通讯作者: 李清寒 E-mail:lqhchem@163.com
  • 基金资助:

    四川省科技厅科技支撑计划(No.2015NZ0033)资助项目.

Recent Advance of Palladium-Catalyzed Cross-Coupling Reactions of Organoalanes with Electrophiles Reagents

Li Qinghan, Shao Xuebei, Zhang Gang, Ding Yong, Yang Xuejun, Chen Feng   

  1. College of Chemistry and Environmental Protection Engineering, Southwest Minzu University, Chengdu 610041
  • Received:2017-06-25 Revised:2017-10-23 Online:2018-04-24 Published:2017-11-15
  • Contact: 10.6023/cjoc201709041 E-mail:lqhchem@163.com
  • Supported by:

    Project supported by the Sichuan Provincial Department of Science and Technology (No. 2015NZ0033).

Organoaluminum compounds are excellent nucleophiles for organic reactions because of their high reactivities, the high Lewis acidity of the aluminum center, and their low toxicities. Therefore, organoalanes are widely applied in cross-coupling reactions. In this paper, recent research results about the organoaluminum reagents applied in cross-coupling reactions catalyzed by palladium are reviewed, involving various reaction systems.

Key words: palladium, organoalanes, cross-coupling reaction, catalyze