Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (10): 2754-2760.DOI: 10.6023/cjoc201804011 Previous Articles     Next Articles

Notes

联萘酚功能化多孔有机聚合物催化的不对称加成反应

孔胜男, 钱雪峰, 舒谋海, 肖文德   

  1. 上海交通大学化学化工学院 上海 200240
  • 收稿日期:2018-04-08 修回日期:2018-05-25 出版日期:2018-10-25 发布日期:2018-06-07
  • 通讯作者: 舒谋海,E-mail:mhshu@sjtu.edu.cn E-mail:mhshu@sjtu.edu.cn
  • 基金资助:

    国家自然科学基金(No.21271129)资助项目.

Asymmetric Addition Reaction Catalyzed by 1- (2-Hydroxynaphtha-len-1-yl)naphthalen-2-ol Functionalized Porous Organic Polymer

Kong Shengnan, Qian Xuefeng, Shu Mouhai, Xiao Wende   

  1. School of Chemistry & Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240
  • Received:2018-04-08 Revised:2018-05-25 Online:2018-10-25 Published:2018-06-07
  • Contact: 10.6023/cjoc201804011 E-mail:mhshu@sjtu.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21271129).

A functionalized porous organic polymer POP-BINOL has been prepared and characterized by various techniques including carbon-13 cross-polarization magic-angle spinning nuclear magnetic resonance (13C CP/MAS NMR), fourier transform infrared spectroscopy (FT-IR), powder X-ray diffraction (pXRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), nitrogen adsorption and thermogravimetric analysis (TG). After being treated with Ti (OiPr)4, the composite material could be used as highly effective and reusable heterogeneous catalyst for asymmetric diethylzinc addition to aldehydes with medium and upper ee value.

Key words: porous organic polymers, BINOL, heterogeneous catalysis, asymmetric addition reaction