Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (11): 2896-2926.DOI: 10.6023/cjoc201804027 Previous Articles     Next Articles

Special Issue: 元素有机化学合辑2018-2019



吴瑶a, 豆正杰a, 吴彩梅b, 陈华保c, 张祖民a, 王显祥a, 殷中琼d, 宋旭d, 贺常亮d, 乐贵洲a   

  1. a 四川农业大学理学院 雅安 625014;
    b 四川农业大学动物营养研究所 成都 611130;
    c 四川农业大学农学院 成都 611130;
    d 四川农业大学动物医学院 成都 611130
  • 收稿日期:2018-04-15 修回日期:2018-06-19 发布日期:2018-07-05
  • 通讯作者: 乐贵洲
  • 基金资助:


Application of Mesitylboronic Acid and Its Esters in Coupling Reactions

Wu Yaoa, Dou Zhengjiea, Wu Caimeib, Chen Huabaoc, Zhang Zumina, Wang Xianxianga, Yin Zhongqiongd, Song Xud, He Changliangd, Yue Guizhoua   

  1. a College of Science, Sichuan Agricultural University, Ya'an 625014;
    b Animal Nutrition Institute, Sichuan Agricultural University, Chengdu 611130;
    c College of Agricultural Sciences, Sichuan Agricultural University, Chengdu 611130;
    d College of Veterinary Medicine, Sichuan Agricultural University, Chengdu 611130
  • Received:2018-04-15 Revised:2018-06-19 Published:2018-07-05
  • Supported by:

    Project supported by the Science & Technology Department of Sichuan Province (No. 2012JY0118) and the Sichuan Agricultural University.

Organic boronic reagents have played a critical role in the field of organic synthesis, especially Suzuki coupling, since they were founded. In return, all kinds of transition metal (Pd, Ni, Rh, Au etc.)-catalyzed coupling reactions have given a big push for the development and application of organic boronic reagents. 2,4,6-Mesitylboronic acid was used widely in various coupling reactions, including Suzuiki reaction, aromatic C-H activation, oxidative Heck reaction, carbonlation, decarboxylation, photoredox reaction and other C-X (C-N, C-S, C-Se) bonding reaction, which was used to synthesize functional materials, ligands and drug molecules. This paper includes two aspects:(1) reviewing the application of mesityl boronic acid and its ester in coupling reaction, and (2) making our points and respecting for this field.

Key words: mesitylboronic acid, coupling reaction, C-H activiation, synthesis