Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (1): 15-27.DOI: 10.6023/cjoc201809037 Previous Articles     Next Articles

Special Issue: 庆祝陈庆云院士九十华诞

Reviews

镍催化的烯丙基取代反应研究进展

张慧君a, 顾庆b, 游书力a,b   

  1. a 华东理工大学化学与分子工程学院 上海 200237;
    b 中国科学院上海有机化学研究所 金属有机化学国家重点实验室 上海 200032
  • 收稿日期:2018-09-28 修回日期:2018-09-28 出版日期:2019-01-25 发布日期:2018-10-26
  • 通讯作者: 顾庆, 游书力 E-mail:qinggu@sioc.ac.cn;slyou@sioc.ac.cn
  • 基金资助:

    国家重点研发计划(No.2016YFA0202900)、国家重点基础研究发展计划(973计划,No.2015CB856600)、国家自然科学基金(Nos.21332009,21572250,21572252)、中国科学院(Nos.XDB20000000,QYZDY-SSW-SLH012)资助项目.

Recent Advances in Ni-Catalyzed Allylic Substitution Reactions

Zhang Huijuna, Gu Qingb, You Shulia,b   

  1. a School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237;
    b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
  • Received:2018-09-28 Revised:2018-09-28 Online:2019-01-25 Published:2018-10-26
  • Contact: 10.6023/cjoc201809037 E-mail:qinggu@sioc.ac.cn;slyou@sioc.ac.cn
  • Supported by:

    Project supported by the National Key R&D Program of China (No. 2016YFA0202900), the National Basic Research Program of China (973 Program, No. 2015CB856600), the National Natural Science Foundation of China (Nos. 21332009, 21572250, 21572252), and the Chinese Academy Sciences (Nos. XDB20000000, QYZDY-SSW-SLH012).

Transition-metal catalyzed allylic substitution reaction is an important approach for constructing carbon-carbon bond and carbon-heteroatom bond. Due to its cheapness, easy access, and wide applicability in organic synthesis, nickel has attracted intense attention. Over the past 50 years, nickel-catalyzed allylic substitution reactions have been extensively studied. The progresses on nickel-catalyzed allylic substitution reactions and their applications in organic synthesis are summarized according to bond formation and nucleophilic reagent.

Key words: allylic substitution, asymmetric catalysis, nickel, transition metal