Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (6): 1711-1719.DOI: 10.6023/cjoc201902022 Previous Articles     Next Articles

Special Issue: 金属有机化学 有机光催化合辑



代雪梅, 李延军, 张少南, 龚磊   

  1. 福建省化学生物学重点实验室 能源材料化学协同创新中心 厦门大学化学化工学院 厦门 361005
  • 收稿日期:2019-02-21 修回日期:2019-03-27 发布日期:2019-04-11
  • 通讯作者: 龚磊
  • 基金资助:


Visible-Light-Induced[3+2] Annulation of Cyclopropylamines with 1,2-Diketone Derivatives

Dai Xuemei, Li Yanjun, Zhang Shaonan, Gong Lei   

  1. Key Laboratory of Chemical Biology of Fujian Province, Collaborative Innovation Center of Chemistry for Energy Materials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005
  • Received:2019-02-21 Revised:2019-03-27 Published:2019-04-11
  • Contact: 10.6023/cjoc201902022
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21572184), the Natural Science Foundation of Fujian Province (No. 2017J06006), and the Fundamental Research Funds for the Central Universities (No. 20720160027).

A visible-light-induced[3+2] annulation of arylcyclopropylamines and 1,2-diarylethanediones was report. A series of α-amino tetrahydrofuran derivatives were synthesized in moderate to good isolated yields under mild reaction conditions. This method would provide an efficient and convenient approach to α-amino tetrahydrofurans which are potentially important buiding blocks in bioactive compounds.

Key words: photoredox, cyclopropylamines, 1,2-diketone derivatives, [3+2] annulation