Visible-Light Photoredox and Palladium Dual Catalysis in Organic Synthesis

doi:10.6023/cjoc202004045

Abstract

Palladium-catalyzed organic transformations is an important branch of organometallic chemistry. Because it can efficiently construct carbon-carbon bonds and carbon-heteroatom bonds, palladium catalysis has been widely used in synthetic chemistry, material science and pharmaceutical industry. However, some of these reactions suffer from harsh reaction conditions, including high temperature and strong base. On the other hand, the visible-light photoredox catalysis employs the visible light as the energy source to generate highly reactive intermediates and realize many novel transformations, which are rare under the normal thermal reaction conditions, under mild reaction conditions. However, there are also limitations in reaction types and substrate scope in this field. In order to solve such problems in these two fields, organic chemists have merged the visible-light photoredox catalysis and palladium catalysis, realizing a series of novel organic transformations through the electron transfer or energy transfer between photosensitizer and organic palladium complex under mild conditions with high efficiency and selectivity, which has broad substrate scope and great application potential. In these transformations, visible-light photoredox catalysis and palladium catalysis both play their respective roles and cooperate well. The application of visible light photoredox and palladium dual catalysis in organic synthesis is summarized and the future research directions in this field are analyzed, which might help the further development of this field.

Key words: visible-light photoredox catalysis, palladium catalysis, dual catalysis, organic synthesis

Cite this article

Zhou Wenjun, Jiang Yuanxu, Chen Liang, Liu Kaixing, Yu Dagang. Visible-Light Photoredox and Palladium Dual Catalysis in Organic Synthesis[J]. Chinese Journal of Organic Chemistry, 2020, 40(11): 3697-3713.

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可见光与钯协同催化的有机合成化学